{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T06:30:38Z","timestamp":1790836238747,"version":"4.1.0"},"reference-count":47,"publisher":"Wiley","issue":"48","license":[{"start":{"date-parts":[[2017,10,26]],"date-time":"2017-10-26T00:00:00Z","timestamp":1508976000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000781","name":"European Research Council","doi-asserted-by":"publisher","award":["ERC Advanced Grant 742145 B-PhosphoChem"],"award-info":[{"award-number":["ERC Advanced Grant 742145 B-PhosphoChem"]}],"id":[{"id":"10.13039\/501100000781","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004963","name":"Seventh Framework Programme","doi-asserted-by":"publisher","award":["grant agreement No. 604391 Graphene Flagship"],"award-info":[{"award-number":["grant agreement No. 604391 Graphene Flagship"]}],"id":[{"id":"10.13039\/501100004963","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007601","name":"Horizon 2020","doi-asserted-by":"publisher","award":["FET-OPEN 2D-INK"],"award-info":[{"award-number":["FET-OPEN 2D-INK"]}],"id":[{"id":"10.13039\/501100007601","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["DFG-SFB 953 \"Synthetic Carbon Allotropes\", Project A1"],"award-info":[{"award-number":["DFG-SFB 953 \"Synthetic Carbon Allotropes\", Project A1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["DFG-SFB 953 \"Synthetic Carbon Allotropes\", Project C2"],"award-info":[{"award-number":["DFG-SFB 953 \"Synthetic Carbon Allotropes\", Project C2"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100011264","name":"FP7 People: Marie-Curie Actions","doi-asserted-by":"publisher","award":["FP7\/2013-IEF-627386"],"award-info":[{"award-number":["FP7\/2013-IEF-627386"]}],"id":[{"id":"10.13039\/100011264","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001652","name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","doi-asserted-by":"publisher","award":["Emerging Talents Initiative (ETI) grant #WS16-17_Nat_04"],"award-info":[{"award-number":["Emerging Talents Initiative (ETI) grant #WS16-17_Nat_04"]}],"id":[{"id":"10.13039\/501100001652","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,11,27]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid\u2010state as well as vapor\u2010phase reactions. By means of a combination of in\u2005situ X\u2010ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior.<\/jats:p>","DOI":"10.1002\/anie.201707462","type":"journal-article","created":{"date-parts":[[2017,10,5]],"date-time":"2017-10-05T09:06:48Z","timestamp":1507194408000},"page":"15267-15273","source":"Crossref","is-referenced-by-count":85,"title":["Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals"],"prefix":"10.1002","volume":"56","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1564-6210","authenticated-orcid":false,"given":"Gonzalo","family":"Abell\u00e1n","sequence":"first","affiliation":[{"name":"Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP) Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU)  Henkestrasse 42 91054 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Neiss","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Theoretische Chemie Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU)  Egerlandstrasse 3 91058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vicent","family":"Lloret","sequence":"additional","affiliation":[{"name":"Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP) Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU)  Henkestrasse 42 91054 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan","family":"Wild","sequence":"additional","affiliation":[{"name":"Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP) Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU)  Henkestrasse 42 91054 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julio C.","family":"Chac\u00f3n\u2010Torres","sequence":"additional","affiliation":[{"name":"Yachay Tech University School of Physical Sciences and Nanotechnology  Urcuqu\u00ed 100119 Ecuador"},{"name":"Institut f\u00fcr Experimental Physik Freie Universit\u00e4t Berlin  Arnimallee 14 14195 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katharina","family":"Werbach","sequence":"additional","affiliation":[{"name":"Faculty of Physics University of Vienna  Strudlhofgasse 4 1090 Vienna Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Filippo","family":"Fedi","sequence":"additional","affiliation":[{"name":"Faculty of Physics University of Vienna  Strudlhofgasse 4 1090 Vienna Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hidetsugu","family":"Shiozawa","sequence":"additional","affiliation":[{"name":"Faculty of Physics University of Vienna  Strudlhofgasse 4 1090 Vienna Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas","family":"G\u00f6rling","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Theoretische Chemie Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU)  Egerlandstrasse 3 91058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Herwig","family":"Peterlik","sequence":"additional","affiliation":[{"name":"Faculty of Physics University of Vienna  Strudlhofgasse 4 1090 Vienna Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas","family":"Pichler","sequence":"additional","affiliation":[{"name":"Faculty of Physics University of Vienna  Strudlhofgasse 4 1090 Vienna Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frank","family":"Hauke","sequence":"additional","affiliation":[{"name":"Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP) Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU)  Henkestrasse 42 91054 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1458-8872","authenticated-orcid":false,"given":"Andreas","family":"Hirsch","sequence":"additional","affiliation":[{"name":"Chair of Organic Chemistry II and Joint Institute of Advanced Materials and Processes (ZMP) Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU)  Henkestrasse 42 91054 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,10,26]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn501226z"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2014.35"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1416581112"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.5b01686"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5EE03732H"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610512"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201610512"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apmt.2016.05.001"},{"key":"e_1_2_2_8_1","doi-asserted-by":"crossref","unstructured":"A. Sajedi-Moghaddam C.\u2005C. Mayorga-Martinez Z. Sofer D. Bou\u0161a E. Saievar-Iranizad M. Pumera J. Phys. Chem. C2017 DOI:https:\/\/doi.org\/10.1021\/acs.jpcc.7b06958.","DOI":"10.1021\/acs.jpcc.7b06958"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl5032293"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1088\/2053-1583\/1\/2\/025001"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5651"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5475"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5458"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2016.42"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2016.171"},{"key":"e_1_2_2_16_1","doi-asserted-by":"crossref","unstructured":"B.\u2005G. M\u00e1rkus F. Simon K. Nagy T. Feh\u00e9r S. Wild G. Abell\u00e1n J.\u2005C. Chac\u00f3n-Torres A. Hirsch F. Hauke Phys. Status Solidi B2017 DOI:https:\/\/doi.org\/10.1002\/pssb.201700232.","DOI":"10.1002\/pssb.201700232"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp506881v"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.112.176801"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaa6486"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.7b00903"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/0378-4363(81)90223-0"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.59.1067"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/0379-6779(87)90940-4"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl504336h"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1246\/cl.140741"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b05482"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4916100"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b11218"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5b03524"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6b04385"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b05052"},{"key":"e_1_2_2_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15036"},{"key":"e_1_2_2_33_1","doi-asserted-by":"publisher","DOI":"10.1080\/00018738100101367"},{"key":"e_1_2_2_34_1","volume-title":"Graphite Intercalation Compounds and Applications","author":"Toshiaki E.","year":"2003"},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.95.087003"},{"key":"e_1_2_2_36_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0365110X65004140"},{"key":"e_1_2_2_37_1","unstructured":"P. Villars K. Cenzual Na3P Crystal Structure: Datasheet from \u201cPAULING FILE Multinaries Edition -2012\u201d in SpringerMaterials (http:\/\/Materials.springer.com\/Isp\/Crystallographic\/Docs\/sd_0458519) Springer Berlin Heidelberg & Material Phases Data System (MPDS) Switzerland & National Institute For Materials Science (NIMS) Japan."},{"key":"e_1_2_2_38_1","unstructured":"P. Villars K. Cenzual K3P Crystal Structure: Datasheet from \u201cPAULING FILE Multinaries Edition -2012\u201d in SpringerMaterials (http:\/\/Materials.springer.com\/Isp\/Crystallographic\/Docs\/sd_0526463) Springer Berlin Heidelberg & Material Phases Data System (MPDS) Switzerland & National Institute For Materials Science (NIMS) Japan."},{"key":"e_1_2_2_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04971"},{"key":"e_1_2_2_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15192"},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn403885k"},{"key":"e_1_2_2_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/pssb.201451477"},{"key":"e_1_2_2_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705071"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201705071"},{"key":"e_1_2_2_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201400401"},{"key":"e_1_2_2_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00761"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201707462","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201707462","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,28]],"date-time":"2023-09-28T16:57:13Z","timestamp":1695920233000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201707462"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2017,10,26]]},"references-count":47,"journal-issue":{"issue":"48","published-print":{"date-parts":[[2017,11,27]]}},"alternative-id":["10.1002\/anie.201707462"],"URL":"https:\/\/doi.org\/10.1002\/anie.201707462","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,10,26]]}}}