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A dual catalytic cycle merging retro\u2010hydrocyanation and cross\u2010coupling enables the conversion of a broad array of aryl chlorides and aryl\/vinyl triflates into their corresponding nitriles. This new reaction provides a strategically distinct approach to the safe preparation of aryl cyanides, which are essential compounds in agrochemistry and medicinal chemistry.<\/jats:p>","DOI":"10.1002\/anie.201707517","type":"journal-article","created":{"date-parts":[[2017,10,9]],"date-time":"2017-10-09T01:52:37Z","timestamp":1507513957000},"page":"15693-15697","source":"Crossref","is-referenced-by-count":129,"title":["Nickel\u2010Catalyzed Cyanation of Aryl Chlorides and Triflates Using Butyronitrile: Merging Retro\u2010hydrocyanation with Cross\u2010Coupling"],"prefix":"10.1002","volume":"56","author":[{"given":"Peng","family":"Yu","sequence":"first","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3968-1424","authenticated-orcid":false,"given":"Bill","family":"Morandi","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,11,7]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","volume-title":"Comprehensive Organic Trans-formations: A Guide to Functional Group Preparations","author":"Larock R. 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