{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T19:45:15Z","timestamp":1791402315473,"version":"4.3.3"},"reference-count":96,"publisher":"Wiley","issue":"47","license":[{"start":{"date-parts":[[2017,10,6]],"date-time":"2017-10-06T00:00:00Z","timestamp":1507248000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001711","name":"Schweizerischer Nationalfonds zur F\u00f6rderung der Wissenschaftlichen Forschung","doi-asserted-by":"publisher","award":["157741"],"award-info":[{"award-number":["157741"]}],"id":[{"id":"10.13039\/501100001711","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2017,11,20]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    An enantioselective C\u2212H amidation of phosphine oxides by using an iridium(III) catalyst bearing an atropchiral cyclopentadienyl (Cp\n                    <jats:sup>x<\/jats:sup>\n                    ) ligand is reported. A very strong cooperative effect between the chiral Cp\n                    <jats:sup>x<\/jats:sup>\n                    ligand and a phthaloyl tert\u2010leucine enabled the transformation. Matched\u2013mismatched cases of the different acid enantiomers are shown. The amidated P\u2010chiral arylphosphine oxides are formed in yields of up to 95\u2009% and with excellent enantioselectivities of up to 99:1 er. Enantiospecific reduction provides access to valuable P\u2010chiral phosphorus(III) compounds.\n                  <\/jats:p>","DOI":"10.1002\/anie.201708440","type":"journal-article","created":{"date-parts":[[2017,9,22]],"date-time":"2017-09-22T04:24:43Z","timestamp":1506054283000},"page":"15088-15092","source":"Crossref","is-referenced-by-count":189,"title":["Cooperative Effects between Chiral Cp\n                    <sup>x<\/sup>\n                    \u2013Iridium(III) Catalysts and Chiral Carboxylic Acids in Enantioselective C\u2212H Amidations of Phosphine Oxides"],"prefix":"10.1002","volume":"56","author":[{"given":"Yun\u2010Suk","family":"Jang","sequence":"first","affiliation":[{"name":"Laboratory of Asymmetric Catalysis and Synthesis EPFL SB ISIC LCSA, BCH 4305  CH-1015 Lausanne Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Dieckmann","sequence":"additional","affiliation":[{"name":"Laboratory of Asymmetric Catalysis and Synthesis EPFL SB ISIC LCSA, BCH 4305  CH-1015 Lausanne Switzerland"},{"name":"Current address: Syngenta Crop Protection AG  Schaffhauserstr. CH-4332 Stein Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5740-8494","authenticated-orcid":false,"given":"Nicolai","family":"Cramer","sequence":"additional","affiliation":[{"name":"Laboratory of Asymmetric Catalysis and Synthesis EPFL SB ISIC LCSA, BCH 4305  CH-1015 Lausanne Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2017,10,6]]},"reference":[{"key":"e_1_2_2_1_1","volume-title":"Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis","year":"2012"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527658862"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604943"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604943"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr5001496"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00031B"},{"key":"e_1_2_2_6_1","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527341542"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja312352p"},{"key":"e_1_2_2_9_1","unstructured":"\u00a0"},{"key":"e_1_2_2_10_2","volume-title":"Phosphorus Ligands in Asymmetric Catalysis: Synthesis and Applications, Vols.\u20051\u20133","year":"2008"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9014887"},{"key":"e_1_2_2_12_1","unstructured":"\u00a0"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800267"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01939a"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5088584"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04624"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b09334"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC02263H"},{"key":"e_1_2_2_19_1","unstructured":"\u00a0"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2016.09.011"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja512029x"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201500201"},{"key":"e_1_2_2_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201500201"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00122"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5QO00142K"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606637"},{"key":"e_1_2_2_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606637"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b00608"},{"key":"e_1_2_2_27_1","unstructured":"For a review see:"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00644"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo4019683"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201404151"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja501014b"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5053768"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol502722j"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310544"},{"key":"e_1_2_2_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201310544"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo5018475"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201508501"},{"key":"e_1_2_2_36_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201508501"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2015.02.065"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511689"},{"key":"e_1_2_2_38_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201511689"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b00662"},{"key":"e_1_2_2_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00692"},{"key":"e_1_2_2_41_1","unstructured":"\u00a0"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00092"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b12964"},{"key":"e_1_2_2_44_1","unstructured":"\u00a0"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08232"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC05092A"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201706013"},{"key":"e_1_2_2_47_3","first-page":"129","year":"2017","journal-title":"Angew. 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