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Rare\u2010earth metallacyclopentadienes play a dual role in the combination of aromatization and Diels\u2013Alder reaction. Compounds <jats:bold>2\u2009a<\/jats:bold>\u2013<jats:bold>c<\/jats:bold> can coordinate to one or two [W(CO)<jats:sub>5<\/jats:sub>] units, yielding <jats:bold>4\u2009a<\/jats:bold>\u2013<jats:bold>c<\/jats:bold> or <jats:bold>5\u2009c<\/jats:bold>, respectively. Furthermore, oxidation of <jats:bold>2\u2009a<\/jats:bold> with <jats:italic>p<\/jats:italic>\u2010benzoquinone produces its corresponding phospholyllithium and regenerated P<jats:sub>4<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/anie.201708897","type":"journal-article","created":{"date-parts":[[2017,11,7]],"date-time":"2017-11-07T02:52:39Z","timestamp":1510023159000},"page":"15886-15890","source":"Crossref","is-referenced-by-count":78,"title":["Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare\u2010Earth\u2010Metal <i>Cyclo<\/i>\u2010P<sub>3<\/sub> Complexes"],"prefix":"10.1002","volume":"56","author":[{"given":"Shanshan","family":"Du","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education College of Chemistry Peking University  Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianhao","family":"Yin","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education College of Chemistry Peking University  Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Chi","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education College of Chemistry Peking University  Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ling","family":"Xu","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education College of Chemistry Peking University  Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0744-2832","authenticated-orcid":false,"given":"Wen\u2010Xiong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education College of Chemistry Peking University  Beijing 100871 China"},{"name":"State Key Laboratory of Elemento-Organic Chemistry Nankai University  Tianjin 300071 P. 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