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Action of LDA on the phosphenium complex does not proceed via attack at phosphorus but rather via C4\u2010deprotonation to yield a unique P\u2010analogue of an \u201cabnormal\u201d carbene. A transmetalation product of the original complex was fully characterized. The C\u2010metalation is also applicable to bis\u2010phosphenium complexes of other metals.<\/jats:p>","DOI":"10.1002\/anie.201709015","type":"journal-article","created":{"date-parts":[[2017,10,5]],"date-time":"2017-10-05T02:08:51Z","timestamp":1507169331000},"page":"15718-15722","source":"Crossref","is-referenced-by-count":29,"title":["Variable Reactivity of a N\u2010Heterocyclic Phosphenium Complex: P\u2212C Bond Activation or \u201cAbnormal\u201d Deprotonation"],"prefix":"10.1002","volume":"56","author":[{"given":"Michael","family":"Gediga","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Simon H.","family":"Schlindwein","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Johannes","family":"Bender","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1677-0109","authenticated-orcid":false,"given":"Martin","family":"Nieger","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Helsinki, P.O Box 55  00014 University of Helsinki Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9196-0466","authenticated-orcid":false,"given":"Dietrich","family":"Gudat","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2017,11,3]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00001a054"},{"key":"e_1_2_2_2_1","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b107881j"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic010714q"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1178206"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)00765-8"},{"key":"e_1_2_2_7_1","unstructured":"\u00a0"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja973241o"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/b204422f"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/om900444z"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108813"},{"key":"e_1_2_2_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201108813"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc17870b"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/om400585b"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/c4cc00846d"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b00686"},{"key":"e_1_2_2_16_1","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja106631r"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc52101j"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT00954A"},{"key":"e_1_2_2_20_1","unstructured":"Reviews:"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.08.006"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr8005087"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.09.006"},{"key":"e_1_2_2_24_1","unstructured":"\u00a0"},{"key":"e_1_2_2_25_2","first-page":"623","volume":"312","author":"Litvinov I. 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