{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T22:12:12Z","timestamp":1791929532672,"version":"4.3.4"},"reference-count":88,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2018,2,21]],"date-time":"2018-02-21T00:00:00Z","timestamp":1519171200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,7,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Direct functionalization of the benzylic C\u2212H bond of diarylmethanes is an important strategy for the synthesis of diarylmethine\u2010containing compounds. However, the methods developed to date for this purpose require a stoichiometric amount (usually more) of either a strong base or an oxidant. Reported here is the first catalytic benzylic C\u2212H bond addition of diarylmethanes to styrenes and conjugated dienes. A potassium zincate complex, generated from potassium benzyl and zinc amide, acts as a catalyst and displays good activity and chemoselectivity. Considering the atom economy of the reaction and the ready availability of the catalyst, this reaction constitutes a practical, efficient method for diarylalkane synthesis.<\/jats:p>","DOI":"10.1002\/anie.201713165","type":"journal-article","created":{"date-parts":[[2018,2,2]],"date-time":"2018-02-02T13:42:59Z","timestamp":1517578979000},"page":"8245-8249","source":"Crossref","is-referenced-by-count":70,"title":["Potassium\u2010Zincate\u2010Catalyzed Benzylic C\u2212H Bond Addition of Diarylmethanes to Styrenes"],"prefix":"10.1002","volume":"57","author":[{"given":"Yu\u2010Feng","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory and Institute of Elemento-Organic Chemistry College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dan\u2010Dan","family":"Zhai","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento-Organic Chemistry College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiang\u2010Yu","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento-Organic Chemistry College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0686-4945","authenticated-orcid":false,"given":"Bing\u2010Tao","family":"Guan","sequence":"additional","affiliation":[{"name":"State Key Laboratory and Institute of Elemento-Organic Chemistry College of Chemistry Nankai University  Tianjin 300071 China"},{"name":"Collaborative Innovation Center of Chemical Science and Engineering Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,2,21]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"For reviews see:"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.toxicon.2004.05.008"},{"key":"e_1_2_2_3_2","first-page":"454","volume":"35","author":"Schmidt F.","year":"2006","journal-title":"Chem. 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