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These species are highly active intermediates in the copper\u2010catalysed direct C\u2212H amination and nitrene transfer. Novel perfluoroalkyl\u2010pyrazolyl\u2010 and pyridinyl\u2010containing ligands were synthesized to coordinate to a reactive copper nitrene centre. Four distinct copper tosyl nitrenes were prepared at low temperatures by the reaction with SO<jats:sub>2<\/jats:sub><jats:italic>t<\/jats:italic>BuPhINTs and copper(I) acetonitrile complexes. Their stoichiometric reactivity has been elucidated regarding the imination of phosphines and the aziridination of styrenes. The formation and thermal decay of the copper nitrenes were investigated by UV\/Vis spectroscopy of the highly coloured species. Additionally, the compounds were studied by cryo\u2010UHR\u2010ESI mass spectrometry and DFT calculations. 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