{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T14:54:15Z","timestamp":1778079255678,"version":"3.51.4"},"reference-count":108,"publisher":"Wiley","issue":"17","license":[{"start":{"date-parts":[[2018,3,15]],"date-time":"2018-03-15T00:00:00Z","timestamp":1521072000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100006510","name":"Duke University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006510","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["GM118786"],"award-info":[{"award-number":["GM118786"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000879","name":"Alfred P. Sloan Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000879","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100001082","name":"Camille and Henry Dreyfus Foundation","doi-asserted-by":"publisher","award":["TC-16-032"],"award-info":[{"award-number":["TC-16-032"]}],"id":[{"id":"10.13039\/100001082","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,4,16]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>\u03b1\u2010Vinylation of phosphonates, phosphine oxides, sulfones, sulfonamides, and sulfoxides has been achieved by selective C\u2212H zincation and copper\u2010catalyzed C(sp<jats:sup>3<\/jats:sup>)\u2212C(sp<jats:sup>2<\/jats:sup>) cross\u2010coupling reaction using vinylphenyliodonium salts. The vinylation transformation proceeds in high efficiency and stereospecificity under mild reaction conditions. This zincative cross\u2010coupling reaction represents a general alkenylation strategy, which is also applicable for \u03b1\u2010alkenylation of esters, amides, and nitriles in the synthesis of \u03b2,\u03b3\u2010unsaturated carbonyl compounds.<\/jats:p>","DOI":"10.1002\/anie.201713278","type":"journal-article","created":{"date-parts":[[2018,2,26]],"date-time":"2018-02-26T05:46:39Z","timestamp":1519623999000},"page":"4727-4731","source":"Crossref","is-referenced-by-count":32,"title":["Alkenylation of C(sp<sup>3<\/sup>)\u2212H Bonds by Zincation\/Copper\u2010Catalyzed Cross\u2010Coupling with Iodonium Salts"],"prefix":"10.1002","volume":"57","author":[{"given":"Chuan","family":"Liu","sequence":"first","affiliation":[{"name":"French Family Science Center Department of Chemistry Duke University  124 Science Drive Durham NC 27708 USA"},{"name":"Current address: HitGen Ltd. Tianfu Life Science Park  88 South Keyuan Road Chengdu 610041 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6803-9556","authenticated-orcid":false,"given":"Qiu","family":"Wang","sequence":"additional","affiliation":[{"name":"French Family Science Center Department of Chemistry Duke University  124 Science Drive Durham NC 27708 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,3,15]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"Selected 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see:"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200803611"},{"key":"e_1_2_2_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200803611"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja8009428"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol101885t"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1017046"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol401377q"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja508067c"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja506885s"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201601320"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6OB02269C"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201603832"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja303442q"},{"key":"e_1_2_2_17_1","unstructured":"For 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see:"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300634"},{"key":"e_1_2_2_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200300634"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar7001123"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja030415v"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460044"},{"key":"e_1_2_2_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460044"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja104505t"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja201827j"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja500666h"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja511778a"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b02372"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature22307"},{"key":"e_1_2_2_31_1","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1010866"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2015586"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja501689j"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol503248f"},{"key":"e_1_2_2_36_1","unstructured":"\u00a0"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja406356c"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja303116v"},{"key":"e_1_2_2_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b02785"},{"key":"e_1_2_2_40_1","unstructured":"For selected examples see:"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol7019839"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol900131q"},{"key":"e_1_2_2_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201202798"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b02945"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201505895"},{"key":"e_1_2_2_45_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201505895"},{"key":"e_1_2_2_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol401747u"},{"key":"e_1_2_2_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b00815"},{"key":"e_1_2_2_48_1","unstructured":"Radical vinylation reactions were also reported. see:"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b01053"},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00909"},{"key":"e_1_2_2_51_1","unstructured":"\u00a0"},{"key":"e_1_2_2_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201303724"},{"key":"e_1_2_2_52_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201303724"},{"key":"e_1_2_2_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201501995"},{"key":"e_1_2_2_53_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201501995"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507130"},{"key":"e_1_2_2_54_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201507130"},{"key":"e_1_2_2_55_1","unstructured":"For selected reviews see:"},{"key":"e_1_2_2_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/b701864a"},{"key":"e_1_2_2_57_2","doi-asserted-by":"publisher","DOI":"10.15227\/orgsyn.086.0308"},{"key":"e_1_2_2_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200904689"},{"key":"e_1_2_2_58_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200904689"},{"key":"e_1_2_2_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja801767s"},{"key":"e_1_2_2_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol301939w"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja305100g"},{"key":"e_1_2_2_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201301449"},{"key":"e_1_2_2_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201302358"},{"key":"e_1_2_2_63_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201302358"},{"key":"e_1_2_2_64_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC01636C"},{"key":"e_1_2_2_65_1","unstructured":"For selected references see:"},{"key":"e_1_2_2_66_2","doi-asserted-by":"publisher","DOI":"10.1039\/b509190j"},{"key":"e_1_2_2_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja060489h"},{"key":"e_1_2_2_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/om700475t"},{"key":"e_1_2_2_69_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200701984"},{"key":"e_1_2_2_69_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200701984"},{"key":"e_1_2_2_70_2","doi-asserted-by":"publisher","DOI":"10.1039\/b815903c"},{"key":"e_1_2_2_71_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol400248e"},{"key":"e_1_2_2_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol300517q"},{"key":"e_1_2_2_73_1","unstructured":"\u00a0"},{"key":"e_1_2_2_74_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308890"},{"key":"e_1_2_2_74_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308890"},{"key":"e_1_2_2_75_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC49296F"},{"key":"e_1_2_2_76_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b02550"},{"key":"e_1_2_2_77_1","unstructured":"See the Supporting Information for the proposed mechanism and related control experiments."},{"key":"e_1_2_2_78_1","unstructured":"\u00a0"},{"key":"e_1_2_2_79_2","doi-asserted-by":"crossref","first-page":"629","DOI":"10.2174\/092986730607220401124820","volume":"6","author":"Pankiewicz K. W.","year":"1999","journal-title":"Curr. Med. Chem."},{"key":"e_1_2_2_80_2","doi-asserted-by":"publisher","DOI":"10.2174\/092986706778521896"},{"key":"e_1_2_2_81_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2006.03.097"},{"key":"e_1_2_2_82_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr2002646"},{"key":"e_1_2_2_83_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr2004212"},{"key":"e_1_2_2_84_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar400071v"},{"key":"e_1_2_2_85_1","unstructured":"For examples see:"},{"key":"e_1_2_2_86_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2008.01.030"},{"key":"e_1_2_2_87_2","doi-asserted-by":"publisher","DOI":"10.3184\/030823410X12857514635822"},{"key":"e_1_2_2_88_2","doi-asserted-by":"publisher","DOI":"10.2174\/092986712801323225"},{"key":"e_1_2_2_89_2","doi-asserted-by":"publisher","DOI":"10.2174\/138955713804484749"},{"key":"e_1_2_2_90_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm0400810"},{"key":"e_1_2_2_91_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr800309r"},{"key":"e_1_2_2_92_1","unstructured":"See the Supporting Information for addtional experimental data."},{"key":"e_1_2_2_93_1","unstructured":"\u00a0"},{"key":"e_1_2_2_94_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja015632f"},{"key":"e_1_2_2_95_2","doi-asserted-by":"publisher","DOI":"10.1080\/00945717608057350"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201713278","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201713278","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.201713278","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201713278","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,8,29]],"date-time":"2023-08-29T17:05:02Z","timestamp":1693328702000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201713278"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,3,15]]},"references-count":108,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2018,4,16]]}},"alternative-id":["10.1002\/anie.201713278"],"URL":"https:\/\/doi.org\/10.1002\/anie.201713278","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,3,15]]}}}