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For R=tBu, the organolithium derivative (\u03b7<jats:sup>5<\/jats:sup>\u2010Cp)Fe{\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>\u20101\u2010(ArLiNCHR)\u20102\u2010(CH<jats:sub>2<\/jats:sub>NMe<jats:sub>2<\/jats:sub>)} (<jats:bold>2<\/jats:bold>) was isolated. Compound <jats:bold>2<\/jats:bold> reacts with GeCl<jats:sub>2<\/jats:sub>\u22c5dioxane and SnCl<jats:sub>2<\/jats:sub> to give the metallylene amide chlorides (\u03b7<jats:sup>5<\/jats:sup>\u2010Cp)Fe{\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>\u20101\u2010(ArMNCHtBu)\u20102\u2010(CH<jats:sub>2<\/jats:sub>NMe<jats:sub>2<\/jats:sub>)} <jats:bold>6<\/jats:bold> (M=GeCl) and <jats:bold>7<\/jats:bold> (M=SnCl), respectively, which each contain three stereogenic centers. The potential of <jats:bold>7<\/jats:bold> as a ligand in transition\u2010metal chemistry is demonstrated by formation of its complex (\u03b7<jats:sup>5<\/jats:sup>\u2010Cp)Fe{\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>\u20101\u2010(ArMNCHtBu)\u20102\u2010(CH<jats:sub>2<\/jats:sub>NMe<jats:sub>2<\/jats:sub>)} [<jats:bold>9<\/jats:bold>, M= Sn(Cl)W(CO)<jats:sub>5<\/jats:sub>]. Treatment of <jats:bold>3<\/jats:bold> with tert\u2010butyllithium at room temperature causes an unprecedented carbon\u2013carbon bond cleavage whereas under kinetic control, lithiation at the Cp\u20103 position takes place, which leads to the isolation of (\u03b7<jats:sup>5<\/jats:sup>\u2010Cp)Fe{\u03b7<jats:sup>5<\/jats:sup>\u2010C<jats:sub>5<\/jats:sub>H<jats:sub>3<\/jats:sub>\u20101\u2010(ArHNCHtBu)\u20102\u2010(CH<jats:sub>2<\/jats:sub>NMe<jats:sub>2<\/jats:sub>)\u20103\u2010SiMe<jats:sub>3<\/jats:sub>} (<jats:bold>10<\/jats:bold>).<\/jats:p>","DOI":"10.1002\/anie.201800128","type":"journal-article","created":{"date-parts":[[2018,2,16]],"date-time":"2018-02-16T09:42:44Z","timestamp":1518774164000},"page":"5544-5547","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["N\u2010Functionalized Ferrocenes: Subvalent Group\u2005XIV Element Chlorides and <i>tert<\/i>\u2010Butyllithium\u2010Induced C\u2212C Bond Cleavage under Mild Conditions"],"prefix":"10.1002","volume":"57","author":[{"given":"Bastian","family":"Nayyar","sequence":"first","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund  Otto-Hahn-Stra\u00dfe 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hazem","family":"Alnasr","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund  Otto-Hahn-Stra\u00dfe 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wolf","family":"Hiller","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund  Otto-Hahn-Stra\u00dfe 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9930-858X","authenticated-orcid":false,"given":"Klaus","family":"Jurkschat","sequence":"additional","affiliation":[{"name":"Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund  Otto-Hahn-Stra\u00dfe 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,4,14]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.06.019"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01003k"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900093s"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9408989"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00313-1"},{"key":"e_1_2_2_8_1","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39760000261"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39740000895"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9760002275"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9760002286"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00340a031"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9850000051"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39790000369"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39730000829"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00513B"},{"key":"e_1_2_2_18_1","unstructured":"\u00a0"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja062928i"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704635"},{"key":"e_1_2_2_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704635"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199608281"},{"key":"e_1_2_2_21_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19961080805"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199516141"},{"key":"e_1_2_2_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951071521"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500695"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0sc00240b"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0347843"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0257164"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic201203u"},{"key":"e_1_2_2_28_1","unstructured":"\u00a0"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr010424r"},{"key":"e_1_2_2_30_2","first-page":"183","volume-title":"Advances in Organometallic Chemistry","author":"Edelmann F. 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