{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T20:19:04Z","timestamp":1790626744074,"version":"4.1.0"},"reference-count":80,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2018,2,22]],"date-time":"2018-02-22T00:00:00Z","timestamp":1519257600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100007486","name":"Universit\u00e9 Paris-Sud","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100007486","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007241","name":"Universit\u00e9 Paris-Saclay","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100007241","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,3,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The borrowing hydrogen strategy has been applied to the ethylation of imines with an air\u2010stable iron complex as precatalyst. This approach opens new perspectives in this area as it enables the synthesis of unsymmetric tertiary amines from readily available substrates and ethanol as a C\n                    <jats:sub>2<\/jats:sub>\n                    building block. A variety of imines bearing electron\u2010rich aryl or alkyl groups at the nitrogen atom could be efficiently reductively alkylated without the need for molecular hydrogen. The mechanism of this reaction, which shows complete selectivity for ethanol over other alcohols, has been studied experimentally and by means of DFT computations.\n                  <\/jats:p>","DOI":"10.1002\/anie.201800328","type":"journal-article","created":{"date-parts":[[2018,2,2]],"date-time":"2018-02-02T05:12:47Z","timestamp":1517548367000},"page":"3228-3232","source":"Crossref","is-referenced-by-count":62,"title":["Iron\u2010Catalyzed Reductive Ethylation of Imines with Ethanol"],"prefix":"10.1002","volume":"57","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3870-5378","authenticated-orcid":false,"given":"Marie","family":"Vayer","sequence":"first","affiliation":[{"name":"ICMMO, CNRS UMR 8182, Univ Paris-Sud Universit\u00e9 Paris-Saclay  B\u00e2t. 420 91405 Orsay cedex France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5840-5471","authenticated-orcid":false,"given":"Sara P.","family":"Morcillo","sequence":"additional","affiliation":[{"name":"ICMMO, CNRS UMR 8182, Univ Paris-Sud Universit\u00e9 Paris-Saclay  B\u00e2t. 420 91405 Orsay cedex France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jennifer","family":"Dupont","sequence":"additional","affiliation":[{"name":"ICMMO, CNRS UMR 8182, Univ Paris-Sud Universit\u00e9 Paris-Saclay  B\u00e2t. 420 91405 Orsay cedex France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1108-9410","authenticated-orcid":false,"given":"Vincent","family":"Gandon","sequence":"additional","affiliation":[{"name":"ICMMO, CNRS UMR 8182, Univ Paris-Sud Universit\u00e9 Paris-Saclay  B\u00e2t. 420 91405 Orsay cedex France"},{"name":"Laboratoire de Chimie Mol\u00e9culaire, CNRS UMR 9168 Ecole Polytechnique Universit\u00e9 Paris-Saclay  route de Saclay 91128 Palaiseau cedex France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6733-5284","authenticated-orcid":false,"given":"Christophe","family":"Bour","sequence":"additional","affiliation":[{"name":"ICMMO, CNRS UMR 8182, Univ Paris-Sud Universit\u00e9 Paris-Saclay  B\u00e2t. 420 91405 Orsay cedex France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,2,22]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","volume-title":"Amines: Synthesis, Properties and Applications","author":"Lawrence S. 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Commun."},{"key":"e_1_2_2_71_1","unstructured":"When the reaction was carried out with amine2\u2009a(0.2\u2009m) in the presence of propanal (20\u2005mol\u2009%) inn-PrOH no alkylation was observed."},{"key":"e_1_2_2_72_1","unstructured":"The volatility of methanal at high temperature could also prevent methylation."},{"key":"e_1_2_2_73_1","doi-asserted-by":"crossref","unstructured":"Global Tertiary Amines Market to 2022: Production Consumption Revenue Gross margin and more DOI:https:\/\/doi.org\/10.1787\/100111226661.","DOI":"10.1787\/100111226661"},{"key":"e_1_2_2_74_1","unstructured":"The use of MgSO4or molecular sieves considerably reduced the catalyst activity."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201800328","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201800328","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,14]],"date-time":"2023-09-14T18:48:58Z","timestamp":1694717338000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201800328"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,2,22]]},"references-count":80,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2018,3,12]]}},"alternative-id":["10.1002\/anie.201800328"],"URL":"https:\/\/doi.org\/10.1002\/anie.201800328","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,2,22]]}}}