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Herein a novel anhydrous OME<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> synthesis route is presented. Catalyzed by trimethyloxonium salts, dimethoxymethane takes up monomeric gaseous formaldehyde instantaneously and forms high purity OME<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> at temperatures of 25\u201330\u2009\u00b0C. This new anhydrous approach using molecular formaldehyde and catalytic amounts of highly active trimethyloxonium salts represents a promising new step towards a sustainable formation of OME<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> emanating from CO<jats:sub>2<\/jats:sub> and H<jats:sub>2<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/anie.201802247","type":"journal-article","created":{"date-parts":[[2018,6,12]],"date-time":"2018-06-12T09:26:16Z","timestamp":1528795576000},"page":"9461-9464","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":43,"title":["Towards a Sustainable Synthesis of Oxymethylene Dimethyl Ether by Homogeneous Catalysis and Uptake of Molecular Formaldehyde"],"prefix":"10.1002","volume":"57","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6160-0550","authenticated-orcid":false,"given":"Andreas","family":"Peter","sequence":"first","affiliation":[{"name":"Department of Inorganic and Analytical Chemistry and 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