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Readily available aliphatic nitro compounds are thereby transformed into N\u2010 and O\u2010functionalized hydroxylamines in a single synthetic operation. Addition of hazardous peroxides is avoided. Instead, the insertion of O\n                    <jats:sub>2<\/jats:sub>\n                    , as the terminal oxidant, into Zn\u2212C bonds provides the necessary peroxides. The required zinc organyls, in turn, are formed through a boron\u2010to\u2010zinc exchange, from an organoboronic ester byproduct of the nitro\u2010to\u2010aminoborane transformation.\n                  <\/jats:p>","DOI":"10.1002\/anie.201803168","type":"journal-article","created":{"date-parts":[[2018,4,9]],"date-time":"2018-04-09T16:54:56Z","timestamp":1523292896000},"page":"5903-5907","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["O\n                    <sub>2<\/sub>\n                    \u2010Mediated Oxidation of Aminoboranes through 1,2\u2010N Migration"],"prefix":"10.1002","volume":"57","author":[{"given":"Marian","family":"Rauser","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University  Landoltweg 1 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel 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