{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,1]],"date-time":"2026-06-01T16:22:49Z","timestamp":1780330969156,"version":"3.54.1"},"reference-count":36,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2018,5,16]],"date-time":"2018-05-16T00:00:00Z","timestamp":1526428800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["BR5269\/1"],"award-info":[{"award-number":["BR5269\/1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002428","name":"Austrian Science Fund","doi-asserted-by":"publisher","award":["M-2005"],"award-info":[{"award-number":["M-2005"]}],"id":[{"id":"10.13039\/501100002428","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,7,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Borosulfates are an ever\u2010expanding class of compounds and the extent of their properties is still elusive. Herein, the first two copper borosulfates Cu[B<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>] and Cu[B(SO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(HSO<jats:sub>4<\/jats:sub>)] are presented, which are structurally related but show different dimensionalities in their substructure: While Cu[B<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>] reveals an anionic chain, <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/anie201803395-math-0001.png\" xlink:title=\"urn:x-wiley:14337851:media:anie201803395:anie201803395-math-0001\"\/>\n[B(SO<jats:sub>4<\/jats:sub>)<jats:sub>4\/2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>, with both a twisted and a unique chair conformation of the B(SO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>B subunits, Cu[B(SO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(HSO<jats:sub>4<\/jats:sub>)] reveals isolated [B<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>(HSO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sup>4\u2212<\/jats:sup> anions showing exclusively a twisted conformation. The complex anion can figuratively be obtained as a cut\u2010out from the anionic chain by protons. Comparative DFT calculations based on magnetochemical measurements complement the experimental studies. Calculation of the p<jats:italic>K<\/jats:italic><jats:sub>a<\/jats:sub>\u2005values of the two conformers of the [B<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>(HSO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sup>4\u2212<\/jats:sup> anion revealed them to be more similar to silicic than to sulfuric acid, highlighting the close relationship to silicates.<\/jats:p>","DOI":"10.1002\/anie.201803395","type":"journal-article","created":{"date-parts":[[2018,4,23]],"date-time":"2018-04-23T11:43:34Z","timestamp":1524483814000},"page":"9548-9552","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Cu[B<sub>2<\/sub>(SO<sub>4<\/sub>)<sub>4<\/sub>] and Cu[B(SO<sub>4<\/sub>)<sub>2<\/sub>(HSO<sub>4<\/sub>)]\u2014Two Silicate Analogue Borosulfates Differing in their Dimensionality: A Comparative Study of Stability and Acidity"],"prefix":"10.1002","volume":"57","author":[{"given":"J\u00f6rn","family":"Bruns","sequence":"first","affiliation":[{"name":"Leopold-Franzens-Universit\u00e4t Innsbruck Institut f\u00fcr Allgemeine Anorganische und Theoretische Chemie  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maren","family":"Podewitz","sequence":"additional","affiliation":[{"name":"Leopold-Franzens-Universit\u00e4t Innsbruck Institut f\u00fcr Allgemeine Anorganische und Theoretische Chemie  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Klaus R.","family":"Liedl","sequence":"additional","affiliation":[{"name":"Leopold-Franzens-Universit\u00e4t Innsbruck Institut f\u00fcr Allgemeine Anorganische und Theoretische Chemie  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9480-3888","authenticated-orcid":false,"given":"Oliver","family":"Janka","sequence":"additional","affiliation":[{"name":"Westf\u00e4lische Wilhelms-Universit\u00e4t M\u00fcnster Institut f\u00fcr Anorganische und Analytische Chemie  Corrensstrasse 30 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rainer","family":"P\u00f6ttgen","sequence":"additional","affiliation":[{"name":"Westf\u00e4lische Wilhelms-Universit\u00e4t M\u00fcnster Institut f\u00fcr Anorganische und Analytische Chemie  Corrensstrasse 30 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2098-6087","authenticated-orcid":false,"given":"Hubert","family":"Huppertz","sequence":"additional","affiliation":[{"name":"Leopold-Franzens-Universit\u00e4t Innsbruck Institut f\u00fcr Allgemeine Anorganische und Theoretische Chemie  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,5,16]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201109237"},{"key":"e_1_2_2_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201109237"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307056"},{"key":"e_1_2_2_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201307056"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201704228"},{"key":"e_1_2_2_5_1","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303012"},{"key":"e_1_2_2_7_2","first-page":"2614","volume":"640","author":"Daub M.","year":"2014","journal-title":"Z. 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