{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T02:14:28Z","timestamp":1791684868356,"version":"4.3.4"},"reference-count":81,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2018,5,2]],"date-time":"2018-05-02T00:00:00Z","timestamp":1525219200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R01 GM100143"],"award-info":[{"award-number":["R01 GM100143"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006483","name":"AbbVie","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100006483","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,5,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>An electrochemical method has been developed for \u03b1\u2010oxygenations of cyclic carbamates by using a bicyclic aminoxyl as a mediator and water as the nucleophile. The mediated electrochemical process enables substrate oxygenation to proceed at a potential that is approximately 1\u2005V lower than the redox potential of the carbamate substrate. This feature allows for functional\u2010group compatibility that is inaccessible with conventional Shono oxidations, which proceed by direct electrochemical substrate oxidation. This reaction also represents the first \u03b1\u2010functionalization of non\u2010activated cyclic carbamates with oxoammonium oxidants.<\/jats:p>","DOI":"10.1002\/anie.201803539","type":"journal-article","created":{"date-parts":[[2018,4,16]],"date-time":"2018-04-16T10:32:21Z","timestamp":1523874741000},"page":"6686-6690","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":147,"title":["Electrochemical Functional\u2010Group\u2010Tolerant Shono\u2010type Oxidation of Cyclic Carbamates Enabled by Aminoxyl Mediators"],"prefix":"10.1002","volume":"57","author":[{"given":"Fei","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Wisconsin-Madison Madison WI 53706 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5325-5387","authenticated-orcid":false,"given":"Mohammad","family":"Rafiee","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Wisconsin-Madison Madison WI 53706 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9000-7665","authenticated-orcid":false,"given":"Shannon S.","family":"Stahl","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Wisconsin-Madison Madison WI 53706 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,5,2]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","volume-title":"Electroorganic Synthesis","author":"Shono T.","year":"1990"},{"key":"e_1_2_2_3_2","volume-title":"Electroorganic Synthesis","author":"Little R. 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Dispos."},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00373a053"},{"key":"e_1_2_2_35_1","unstructured":"For leading references see:"},{"key":"e_1_2_2_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja015823i"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20020617)8:12<2650::AID-CHEM2650>3.0.CO;2-S"},{"key":"e_1_2_2_38_1","unstructured":"Modification of the substrate with an \u201celectroauxiliary\u201d provides a strategy to enhance the substrate scope. For leading references see Ref.\u2005[2b] and:"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)96929-6"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja028663z"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.5796\/electrochemistry.74.672"},{"key":"e_1_2_2_42_1","doi-asserted-by":"publisher","DOI":"10.1246\/cl.1984.1063"},{"key":"e_1_2_2_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2013.10.093"},{"key":"e_1_2_2_44_1","unstructured":"Zeng Little and co-workers (Ref.\u2005[11]) reported a dual-mediator Br\u2212\/TEMPO system for two-phase electrochemical \u03b1-oxygenation but the method was limited to activated 1 2 3 4-tetrahydroisoquinoline derivatives. As shown in Figure\u20051 TEMPO is ineffective with the substrates described in the present study."},{"key":"e_1_2_2_45_1","unstructured":"For examples see:"},{"key":"e_1_2_2_46_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201202379"},{"key":"e_1_2_2_46_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201202379"},{"key":"e_1_2_2_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b00447"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b03042"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b03372"},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b00787"},{"key":"e_1_2_2_51_1","unstructured":"\u00a0"},{"key":"e_1_2_2_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b09672"},{"key":"e_1_2_2_53_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature18008"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201704921"},{"key":"e_1_2_2_54_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201704921"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b09744"},{"key":"e_1_2_2_56_1","unstructured":"For representative leading references see:"},{"key":"e_1_2_2_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5098379"},{"key":"e_1_2_2_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201300016"},{"key":"e_1_2_2_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b11252"},{"key":"e_1_2_2_60_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature17431"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b00426"},{"key":"e_1_2_2_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b04137"},{"key":"e_1_2_2_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201710659"},{"key":"e_1_2_2_63_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201710659"},{"key":"e_1_2_2_64_1","unstructured":"For early precedents see:"},{"key":"e_1_2_2_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00351a070"},{"key":"e_1_2_2_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00007a031"},{"key":"e_1_2_2_67_1","author":"Nutting J. E.","year":"2018","journal-title":"Chem. 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