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The influence of the solvent (HCN, CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, and aromatic hydrocarbons) on the crystallization process was studied, revealing dimer formation when using HCN or CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>as solvent, whereas aromatic hydrocarbons led to the formation of monomeric arene\u22c5\u22c5HCN\u2212B(C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>adducts, additionally stabilized by \u03b7<jats:sup>6<\/jats:sup>\u2010coordination of the aromatic ring system similar to well\u2010known half\u2010sandwich complexes.<\/jats:p>","DOI":"10.1002\/anie.201804193","type":"journal-article","created":{"date-parts":[[2018,5,17]],"date-time":"2018-05-17T14:34:45Z","timestamp":1526567685000},"page":"9170-9175","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":33,"title":["A Dimer of Hydrogen Cyanide Stabilized by a Lewis Acid"],"prefix":"10.1002","volume":"57","author":[{"given":"Kevin","family":"Bl\u00e4sing","sequence":"first","affiliation":[{"name":"Anorganische Chemie Institut f\u00fcr Chemie Universit\u00e4t Rostock A.-Einstein-Str. 3a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9450-3407","authenticated-orcid":false,"given":"Jonas","family":"Bresien","sequence":"additional","affiliation":[{"name":"Anorganische Chemie Institut f\u00fcr Chemie Universit\u00e4t Rostock A.-Einstein-Str. 3a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ren\u00e9","family":"Labbow","sequence":"additional","affiliation":[{"name":"Anorganische Chemie Institut f\u00fcr Chemie Universit\u00e4t Rostock A.-Einstein-Str. 3a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9060-7065","authenticated-orcid":false,"given":"Axel","family":"Schulz","sequence":"additional","affiliation":[{"name":"Anorganische Chemie Institut f\u00fcr Chemie Universit\u00e4t Rostock A.-Einstein-Str. 3a 18059 Rostock Germany"},{"name":"Materialdesign Leibniz-Institut f\u00fcr Katalyse, an der Universit\u00e4t Rostock A.-Einstein-Str. 29a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander","family":"Villinger","sequence":"additional","affiliation":[{"name":"Anorganische Chemie Institut f\u00fcr Chemie Universit\u00e4t Rostock A.-Einstein-Str. 3a 18059 Rostock Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,6,19]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"In English \u201cThe ordinary prussic acid should be named hydrogen cyanide\u201d."},{"key":"e_1_2_2_2_1","first-page":"136","author":"Gay-Lussac J. 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