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A range of mono\u2010metal (Co, Fe, Al, Ni, Cu, Zn, Ce), bi\u2010metal (Fe\u2010Co, Co\u2010Zn) and multi\u2010metal (Fe\u2010Co\u2010Ni\u2010Cu\u2010Zn) species can be incorporated into the frameworks of the colloidal spheres. The formation of coordination spheres involves the pre\u2010crosslinking of plant polyphenol (such as tannic acid) by formaldehyde in alkaline ethanol\/water solvents, followed by the aggregation assembly of polyphenol oligomers via metal\u2013ligand crosslinking. The coordination spheres can be used as sensors for the analysis of nucleic acid variants with single\u2010nucleotide discrimination, and a versatile precursor for electrode materials with high electrocatalytic performance.<\/jats:p>","DOI":"10.1002\/anie.201805781","type":"journal-article","created":{"date-parts":[[2018,6,21]],"date-time":"2018-06-21T06:32:30Z","timestamp":1529562750000},"page":"9838-9843","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":192,"title":["Sol\u2013Gel Synthesis of Metal\u2013Phenolic Coordination Spheres and Their Derived Carbon Composites"],"prefix":"10.1002","volume":"57","author":[{"given":"Jing","family":"Wei","sequence":"first","affiliation":[{"name":"School of Life Science and Technology The Key Laboratory of Biomedical Information Engineering of Ministry of Education Xi'an Jiaotong University  Xi'an Shaanxi 710049 P. R. 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