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Taking advantage of the rich coordination chemistry of alkyl phosphines, stibino\u2010phosphonium and stibino\u2010bis(phosphonium) functionalized polymer networks could be generated. Small\u2010molecule stibino\u2010phosphonium and stibino\u2010bis(phosphonium) compounds have been well characterized previously and were used as models for spectroscopic comparison to the macromolecular analogues by NMR and XANES spectroscopy. This work reveals that the physical and electronic properties of the materials can be tuned depending on the type of coordination environment. These materials can be used as ceramic precursors, where the Sb\u2010functionalized polymers influence the composition of the resulting ceramic.<\/jats:p>","DOI":"10.1002\/anie.201806235","type":"journal-article","created":{"date-parts":[[2018,7,16]],"date-time":"2018-07-16T13:40:45Z","timestamp":1531748445000},"page":"13252-13256","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Antimony\u2010Functionalized Phosphine\u2010Based Photopolymer Networks"],"prefix":"10.1002","volume":"57","author":[{"given":"Vanessa A.","family":"B\u00e9land","sequence":"first","affiliation":[{"name":"Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research the University of Western Ontario  1151 Richmond Street London Ontario N6A 5B7 Canada"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhiqiang","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry and 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