{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T03:04:53Z","timestamp":1791860693485,"version":"4.3.4"},"reference-count":54,"publisher":"Wiley","issue":"51","license":[{"start":{"date-parts":[[2018,11,27]],"date-time":"2018-11-27T00:00:00Z","timestamp":1543276800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21702098"],"award-info":[{"award-number":["21702098"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,12,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Organoboron compounds are versatile synthetic building blocks. We herein report a new strategy, a photochemical gold\u2010catalyzed chemo\u2010selective Hiyama arylation of B,Si bifunctionalized reagents with diazonium salts, which is orthogonal to common strategies and therefore a unique tool for synthesis of valuable biarylboronates. With this new methodology a wide array of diversely functionalized sp\n                    <jats:sup>2<\/jats:sup>\n                    \u2010 and sp\n                    <jats:sup>3<\/jats:sup>\n                    \u2010hybridized biarylboronates were obtained. Notably, the synergism of gold catalysis with copper catalysis or palladium catalysis, allows for one\u2010pot iterative C\u2212X (heteroatom) and C\u2212C couplings for the rapid assembly of several simple fragments to relatively complex molecules. Mechanistic studies indicated that photosensitizer\u2010free conditions were superior to gold\/Ru(bpy)\n                    <jats:sub>3<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    dual catalysis.\n                  <\/jats:p>","DOI":"10.1002\/anie.201806427","type":"journal-article","created":{"date-parts":[[2018,10,10]],"date-time":"2018-10-10T00:15:23Z","timestamp":1539130523000},"page":"16648-16653","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":108,"title":["Light\u2010Induced Gold\u2010Catalyzed Hiyama Arylation: A Coupling Access to Biarylboronates"],"prefix":"10.1002","volume":"57","author":[{"given":"Jin","family":"Xie","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kohei","family":"Sekine","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sina","family":"Witzel","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Petra","family":"Kr\u00e4mer","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"Rudolph","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frank","family":"Rominger","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6720-8602","authenticated-orcid":false,"given":"A. Stephen K.","family":"Hashmi","sequence":"additional","affiliation":[{"name":"Organisch-Chemisches Institut Universit\u00e4t Heidelberg  Im Neuenheimer Feld 270 69120 Heidelberg Germany"},{"name":"Chemistry Department Faculty of Science King Abdulaziz University  Jeddah 21589 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,11,27]]},"reference":[{"key":"e_1_2_2_1_1","volume-title":"Synthesis of biaryls","author":"Cepanec I.","year":"2010"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107017"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201107017"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar9000058"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00567"},{"key":"e_1_2_2_5_1","volume-title":"Boronic acids: preparation and applications in organic synthesis and medicine","author":"Yoshida K.","year":"2005"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60197H"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0716204"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaa5414"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol702420x"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja067975p"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja408712e"},{"key":"e_1_2_2_12_1","first-page":"12790","volume":"138","author":"Kumar R.","year":"2016","journal-title":"J. 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