{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:29:37Z","timestamp":1786976977800,"version":"build-2736575974"},"reference-count":45,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2018,8,6]],"date-time":"2018-08-06T00:00:00Z","timestamp":1533513600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004281","name":"Narodowe Centrum Nauki","doi-asserted-by":"publisher","award":["UMO-2014\/15\/D\/ST5\/02580"],"award-info":[{"award-number":["UMO-2014\/15\/D\/ST5\/02580"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,9,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Nitrous oxide is considered a poor ligand, and therefore only a handful of well\u2010defined metal\u2013N\n                    <jats:sub>2<\/jats:sub>\n                    O complexes are known. Oxidation of copper powder with an extreme oxidant, [Ag\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>2<\/jats:sub>\n                    ][\n                    <jats:bold>An<\/jats:bold>\n                    ]\n                    <jats:sub>2<\/jats:sub>\n                    ([\n                    <jats:bold>An<\/jats:bold>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    =[Al(OC(CF\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) in perfluorinated hexane leads to Cu\n                    <jats:sup>I<\/jats:sup>\n                    [\n                    <jats:bold>An<\/jats:bold>\n                    ], the first auxiliary ligand\u2010free Cu\n                    <jats:sup>I<\/jats:sup>\n                    salt of the perfluorinated alkoxyaluminate anion. The compound is capable of forming a stable and crystalline complex with nitrous oxide, Cu(N\n                    <jats:sub>2<\/jats:sub>\n                    O)[\n                    <jats:bold>An<\/jats:bold>\n                    ], where the Cu\u2212N\n                    <jats:sub>2<\/jats:sub>\n                    O bond is by far the strongest among all other molecular metal\u2013N\n                    <jats:sub>2<\/jats:sub>\n                    O complexes known. Thorough characterization of the compounds together with the crystal structure of Cu(N\n                    <jats:sub>2<\/jats:sub>\n                    O)[\n                    <jats:bold>An<\/jats:bold>\n                    ] complex supported with DFT calculations are presented. These give insight into the bonding in the Cu\n                    <jats:sup>+<\/jats:sup>\n                    \u2013N\n                    <jats:sub>2<\/jats:sub>\n                    O system and confirm N\u2010end coordination of the ligand.\n                  <\/jats:p>","DOI":"10.1002\/anie.201806836","type":"journal-article","created":{"date-parts":[[2018,7,19]],"date-time":"2018-07-19T02:57:17Z","timestamp":1531969037000},"page":"11697-11700","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":41,"title":["A Stable Crystalline Copper(I)\u2013N\n                    <sub>2<\/sub>\n                    O Complex Stabilized as the Salt of a Weakly Coordinating Anion"],"prefix":"10.1002","volume":"57","author":[{"given":"Vadim","family":"Zhuravlev","sequence":"first","affiliation":[{"name":"Faculty of Physics University of Warsaw  Pasteura 5 02093 Warsaw Poland"},{"name":"Centre of New Technologies University of Warsaw  Banacha 2c 02097 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6681-6721","authenticated-orcid":false,"given":"Przemys\u0142aw J.","family":"Malinowski","sequence":"additional","affiliation":[{"name":"Centre of New Technologies University of Warsaw  Banacha 2c 02097 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,8,6]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.05.026"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00339C"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1956"},{"key":"e_1_2_2_4_1","unstructured":"\u00a0"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1176985"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-8-389-2008"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(98)00254-9"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905364"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200905364"},{"key":"e_1_2_2_9_1","unstructured":"\u00a0"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-3373(02)00073-5"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2017.06.269"},{"key":"e_1_2_2_12_1","unstructured":"Examples:"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0SC00398K"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja904377v"},{"key":"e_1_2_2_15_1","unstructured":"\u00a0"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201106589"},{"key":"e_1_2_2_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201106589"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4030287"},{"key":"e_1_2_2_18_1","unstructured":"\u00a0"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CP04474G"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201704645"},{"key":"e_1_2_2_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201704645"},{"key":"e_1_2_2_21_1","unstructured":"\u00a0"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01052a069"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic049302i"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja110798w"},{"key":"e_1_2_2_25_1","unstructured":"\u00a0"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603913"},{"key":"e_1_2_2_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201603913"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201603741"},{"key":"e_1_2_2_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201603741"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(03)00159-6"},{"key":"e_1_2_2_29_1","unstructured":"\u00a0"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400388t"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja411500p"},{"key":"e_1_2_2_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2005.12.042"},{"key":"e_1_2_2_33_1","unstructured":"\u00a0"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/b710899k"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200900244"},{"key":"e_1_2_2_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b02674"},{"key":"e_1_2_2_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20010119)7:2<490::AID-CHEM490>3.0.CO;2-I"},{"key":"e_1_2_2_38_1","unstructured":"Note that Ag[An] is stable during prolonged sonication in C6F14at ca. 60\u201365\u2009\u00b0C reached during the work of the ultrasonic bath used in the studies from Ref.\u2005[13]."},{"key":"e_1_2_2_39_1","unstructured":"The calculated\u03bd(N\u2212N) is in fairly good agreement with the vibrations of N2O adsorbed on Na and Ag-ZSM5 zeolites reported in Ref.\u2005[14]."},{"key":"e_1_2_2_40_1","unstructured":"For completeness we have performed also geometry optimizations of N2O with point charges instead of metal cations and bond lengths in N2O remain almost unchanged as compared to M+-N2O. For details see the Supporting Information."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201806836","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201806836","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.201806836","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201806836","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,10]],"date-time":"2023-09-10T05:34:24Z","timestamp":1694324064000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201806836"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,8,6]]},"references-count":45,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2018,9,3]]}},"alternative-id":["10.1002\/anie.201806836"],"URL":"https:\/\/doi.org\/10.1002\/anie.201806836","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,8,6]]},"assertion":[{"value":"2018-06-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2018-08-06","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}