{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T20:00:26Z","timestamp":1791316826901,"version":"4.3.1"},"reference-count":61,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2018,9,13]],"date-time":"2018-09-13T00:00:00Z","timestamp":1536796800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,10,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Layered transition metal compounds represent a major playground to explore unconventional electric or magnetic properties. In that framework, topochemical approaches that mostly preserve the topology of layered reactants have been intensively investigated to tune properties and\/or design new materials. Topochemical reactions often involve the insertion or deinsertion of a chemical element accompanied by a change of oxidation state of the cations only. Conversely, cases where anions play the role of redox centers are very scarce. Here we show that the insertion of copper into two dimensional precursors containing chalcogen dimers (Q<jats:sub>2<\/jats:sub>)<jats:sup>2\u2212<\/jats:sup> (Q=S, Se) can produce layered materials with extended (CuQ) sheets. The reality of this topochemical reaction is demonstrated here for different pristine materials, namely La<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>, Ba<jats:sub>2<\/jats:sub>F<jats:sub>2<\/jats:sub>S<jats:sub>2<\/jats:sub>, and LaSe<jats:sub>2<\/jats:sub>. Therefore, this work opens up a new synthetic strategy to design layered transition metal compounds from precursors containing polyanionic redox centers.<\/jats:p>","DOI":"10.1002\/anie.201807927","type":"journal-article","created":{"date-parts":[[2018,8,22]],"date-time":"2018-08-22T15:57:27Z","timestamp":1534953447000},"page":"13618-13623","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["A Topochemical Approach to Synthesize Layered Materials Based on the Redox Reactivity of Anionic Chalcogen Dimers"],"prefix":"10.1002","volume":"57","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8358-1629","authenticated-orcid":false,"given":"Shunsuke","family":"Sasaki","sequence":"first","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dalel","family":"Driss","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elodie","family":"Grange","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean\u2010Yves","family":"Mevellec","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria Teresa","family":"Caldes","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Catherine","family":"Guillot\u2010Deudon","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sylvian","family":"Cadars","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beno\u00eet","family":"Corraze","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2430-9542","authenticated-orcid":false,"given":"Etienne","family":"Janod","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"St\u00e9phane","family":"Jobic","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5720-4395","authenticated-orcid":false,"given":"Laurent","family":"Cario","sequence":"additional","affiliation":[{"name":"Institut des Mat\u00e9riaux Jean Rouxel (IMN) Universit\u00e9 de Nantes CNRS  2 rue de la Houssini\u00e8re, BP 32229 44322 Nantes Cedex 3 France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,9,13]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/nphys2942"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/nphys1759"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature14165"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00758E"},{"key":"e_1_2_2_6_1","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm010689m"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201002274"},{"key":"e_1_2_2_9_1","unstructured":"\u00a0"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3091438"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature01450"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3478"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2016.04.008"},{"key":"e_1_2_2_14_1","unstructured":"\u00a0"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja991573i"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature06382"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja309798e"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja910103d"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1246\/cl.130581"},{"key":"e_1_2_2_20_1","unstructured":"\u00a0"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.1997.7564"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201403536"},{"key":"e_1_2_2_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201403536"},{"key":"e_1_2_2_23_1","unstructured":"\u00a0"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404476"},{"key":"e_1_2_2_24_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404476"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat1002"},{"key":"e_1_2_2_26_1","unstructured":"\u00a0"},{"key":"e_1_2_2_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/0925-8388(92)90269-F"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.23-3043"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1139\/v68-351"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19960020904"},{"key":"e_1_2_2_31_1","unstructured":"\u00a0"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201705197"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssi.2005.04.007"},{"key":"e_1_2_2_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar00020a002"},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-4596(81)90199-7"},{"key":"e_1_2_2_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-4596(77)90047-0"},{"key":"e_1_2_2_37_1","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.24-2983"},{"key":"e_1_2_2_38_1","unstructured":"\u00a0"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740882001988"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1107\/S056774088200199X"},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108270189013375"},{"key":"e_1_2_2_42_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF00364913"},{"key":"e_1_2_2_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT03611F"},{"key":"e_1_2_2_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00230a005"},{"key":"e_1_2_2_45_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108768190011041"},{"key":"e_1_2_2_46_1","unstructured":"\u00a0"},{"key":"e_1_2_2_47_2","first-page":"789","volume":"292","author":"Palazzi M.","year":"1981","journal-title":"C. R. Seances Acad. Sci. Ser. C"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic902521r"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-6090(02)00198-0"},{"key":"e_1_2_2_50_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.64.245211"},{"key":"e_1_2_2_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2003.09.007"},{"key":"e_1_2_2_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2011.11.151"},{"key":"e_1_2_2_53_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1007976213743"},{"key":"e_1_2_2_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4DT00203B"},{"key":"e_1_2_2_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-3697(91)90188-6"},{"key":"e_1_2_2_56_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.432711"},{"key":"e_1_2_2_57_1","unstructured":"M. Koyano K. Takase T. Shimizu K. Makihara Y. Takahashi Y. Takano K. Sekizawa S. Katayama Phys. Semicond. 2002: Proc. 26thInt. Conf. Edinburgh 29 July to 2 August 2002 D20."},{"key":"e_1_2_2_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-3697(83)90124-5"},{"key":"e_1_2_2_59_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.1834893"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201807927","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201807927","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,14]],"date-time":"2023-09-14T05:57:31Z","timestamp":1694671051000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201807927"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2018,9,13]]},"references-count":61,"journal-issue":{"issue":"41","published-print":{"date-parts":[[2018,10,8]]}},"alternative-id":["10.1002\/anie.201807927"],"URL":"https:\/\/doi.org\/10.1002\/anie.201807927","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2018,9,13]]},"assertion":[{"value":"2018-07-11","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2018-09-13","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}