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Mixed ternary non\u2010metal nitrides, however, have only been sparsely investigated, as preparative chemistry lacks a systematic access, yet. Herein, we report on the highly condensed boron phosphorus nitride BP<jats:sub>3<\/jats:sub>N<jats:sub>6<\/jats:sub>, which was synthesized from (PNCl<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>, NH<jats:sub>4<\/jats:sub>N<jats:sub>3<\/jats:sub> and h\u2010BN in a high\u2010pressure high\u2010temperature reaction. By increasing partial pressure of HCl during synthesis using NH<jats:sub>4<\/jats:sub>Cl, single\u2010crystals of BP<jats:sub>3<\/jats:sub>N<jats:sub>6<\/jats:sub> up to 80\u2005\u03bcm in length were obtained. The unprecedented framework\u2010type structure determined by single\u2010crystal XRD blends structural motifs of both, \u03b1\u2010P<jats:sub>3<\/jats:sub>N<jats:sub>5<\/jats:sub> and c\u2010BN, rendering BP<jats:sub>3<\/jats:sub>N<jats:sub>6<\/jats:sub> a double nitride. The compound was further investigated by Rietveld refinement, EDX, temperature\u2010dependent PXRD, FTIR and solid\u2010state NMR spectroscopy. The formation of BP<jats:sub>3<\/jats:sub>N<jats:sub>6<\/jats:sub> through use of reactive precursors exemplifies an innovative access to mixed non\u2010metal nitrides.<\/jats:p>","DOI":"10.1002\/anie.201808111","type":"journal-article","created":{"date-parts":[[2018,8,8]],"date-time":"2018-08-08T15:17:39Z","timestamp":1533741459000},"page":"13202-13205","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["United in Nitride: The Highly Condensed Boron Phosphorus Nitride BP<sub>3<\/sub>N<sub>6<\/sub>"],"prefix":"10.1002","volume":"57","author":[{"given":"Sebastian","family":"Vogel","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amalina T.","family":"Buda","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4571-8035","authenticated-orcid":false,"given":"Wolfgang","family":"Schnick","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,9,10]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199308061"},{"key":"e_1_2_2_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19931050606"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1151-2916.2000.tb01182.x"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmatprotec.2005.04.010"},{"key":"e_1_2_2_4_1","unstructured":"\u00a0"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2317"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2016.07.030"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/165722b0"},{"key":"e_1_2_2_8_1","unstructured":"\u00a0"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/180332a0"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740869005292"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199718731"},{"key":"e_1_2_2_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091714"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3749(199804)624:4<620::AID-ZAAC620>3.0.CO;2-K"},{"key":"e_1_2_2_14_1","unstructured":"\u00a0"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.12.006"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2017.30"},{"key":"e_1_2_2_17_1","unstructured":"\u00a0"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1745964"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1731679"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010716)40:14<2643::AID-ANIE2643>3.0.CO;2-T"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010716)113:14<2713::AID-ANGE2713>3.0.CO;2-V"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/22493"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.245.4920.841"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm00030a021"},{"key":"e_1_2_2_24_1","unstructured":"\u00a0"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199703281"},{"key":"e_1_2_2_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971090405"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200504193"},{"key":"e_1_2_2_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200504193"},{"key":"e_1_2_2_27_1","unstructured":"\u00a0"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.39.1760"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.55.R10161"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1337623"},{"key":"e_1_2_2_31_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.93.195504"},{"key":"e_1_2_2_32_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.77.094121"},{"key":"e_1_2_2_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200600551"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200600551"},{"key":"e_1_2_2_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm950385y"},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201309020"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201309020"},{"key":"e_1_2_2_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406240"},{"key":"e_1_2_2_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01619a007"},{"key":"e_1_2_2_38_1","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.219.6.330.34633"},{"key":"e_1_2_2_39_1","unstructured":"Crystal data of BP3N6from single-crystal XRD refinement:M=187.78\u2005g\u2009mol\u22121 monoclinic P21\/c(no. 14) a=5.0272(11) b=4.5306(12) andc=17.332(3)\u2005\u00c5 \u03b2=106.387(9)\u00b0 V=378.72(15)\u2005\u00c53 Z=4 \u03c1=3.293\u2005g\u2009cm\u22123 \u03bc=1.43\u2005cm\u22121 Mo-K\u03b1 (\u03bb=0.71073\u2005\u00c5 Bruker D8 Venture) T=293\u2005K 7378 observed reflections 1662 independent reflections 91 parameters Rint=0.0482 R\u03c3=0.0454 R1=0.0369 wR2=0.0966 GoF=1.111 residual electron density 0.737 \u22120.578\u2005e\u2009\u00c5\u22123. Further details on the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe 76344 Eggenstein-Leopoldshafen Germany (fax: (+49)\u20097247-808-666; e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository number CSD-434784."},{"key":"e_1_2_2_40_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-50076-3"},{"key":"e_1_2_2_41_1","unstructured":"\u00a0"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg500498k"},{"key":"e_1_2_2_43_2","unstructured":"V.\u2005A. Blatov A.\u2005P. Shevchenko D.\u2005M. 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