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However, regulatory constraints stemming from the toxic and pyrophoric nature of white phosphorus have significantly limited its accessibility. Herein is described a new approach to white phosphorus storage and release based on a unique example of photolytic reductive elimination of the tetrahedral P<jats:sub>4<\/jats:sub> molecule from a mononuclear cyclo\u2010P<jats:sub>4<\/jats:sub> molybdenum complex. The latter functions as an air\u2010stable, chemically\u2010deactivated source of white phosphorus. The system features efficient photo\u2010release of white phosphorus using inexpensive violet LED sources. Additionally, high\u2010yield recapture of unspent white phosphorus by the molybdenum center can be achieved by post\u2010photolysis heating at convenient temperatures.<\/jats:p>","DOI":"10.1002\/anie.201809042","type":"journal-article","created":{"date-parts":[[2018,10,29]],"date-time":"2018-10-29T10:50:18Z","timestamp":1540810218000},"page":"1779-1783","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Photolytic Reductive Elimination of White Phosphorus from a Mononuclear <i>cyclo<\/i>\u2010P<sub>4<\/sub> Transition Metal Complex"],"prefix":"10.1002","volume":"58","author":[{"given":"Kyle A.","family":"Mandla","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California  San Diego 9500 Gilman Drive MC 0358, La Jolla CA 92093 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Curtis E.","family":"Moore","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California  San Diego 9500 Gilman Drive MC 0358, La Jolla CA 92093 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arnold L.","family":"Rheingold","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California  San Diego 9500 Gilman Drive MC 0358, La Jolla CA 92093 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2099-5984","authenticated-orcid":false,"given":"Joshua S.","family":"Figueroa","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California  San Diego 9500 Gilman Drive MC 0358, La Jolla CA 92093 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2018,11,14]]},"reference":[{"key":"e_1_2_2_1_1","volume-title":"Chemistry of the Elements","author":"Greenwood N. 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