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Here, we describe a chlorocarbene\u2010mediated modification of exfoliated layered arsenic materials. Carbene\u2010based species are highly reactive and offer further possibilities of functionalization. Our approach for modifying the arsenic surface by chlorocarbene generated from organolithium and dichloromethane resulted in a large surface coverage and a highly luminescent functionalized material, opening the door for its application in modern optoelectronic devices.<\/jats:p>","DOI":"10.1002\/anie.201809341","type":"journal-article","created":{"date-parts":[[2018,8,31]],"date-time":"2018-08-31T11:49:20Z","timestamp":1535716160000},"page":"14837-14840","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Covalent Functionalization of Exfoliated Arsenic with Chlorocarbene"],"prefix":"10.1002","volume":"57","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8113-0709","authenticated-orcid":false,"given":"Jiri","family":"Sturala","sequence":"first","affiliation":[{"name":"Department of Inorganic Chemistry University of Chemistry and Technology Prague  Technicka 5 166 28 Prague 6 Czech 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