{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,29]],"date-time":"2025-11-29T23:27:45Z","timestamp":1764458865204,"version":"3.37.3"},"reference-count":50,"publisher":"Wiley","issue":"48","license":[{"start":{"date-parts":[[2018,11,8]],"date-time":"2018-11-08T00:00:00Z","timestamp":1541635200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["PhD studentship (to ADG and JAB)"],"award-info":[{"award-number":["PhD studentship (to ADG and JAB)"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000704","name":"Royal Society of Chemistry","doi-asserted-by":"publisher","award":["Undergraduate Research Bursary (to TAY)"],"award-info":[{"award-number":["Undergraduate Research Bursary (to TAY)"]}],"id":[{"id":"10.13039\/501100000704","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2018,11,26]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A completely inorganic version of one of the most famous organophosphorus compounds, triphenylphosphine, has been prepared. A comparison of the crystal structures of inorganic triphenylphosphine, PBaz<jats:sub>3<\/jats:sub> (where Baz=B<jats:sub>3<\/jats:sub>H<jats:sub>2<\/jats:sub>N<jats:sub>3<\/jats:sub>H<jats:sub>3<\/jats:sub>) and PPh<jats:sub>3<\/jats:sub> shows that they have superficial similarities and furthermore, the Lewis basicities of the two compounds are remarkably similar. However, their oxygenation and hydrolysis reactions are starkly different. PBaz<jats:sub>3<\/jats:sub> reacts quantitatively with water to give PH<jats:sub>3<\/jats:sub> and with the oxidizing agent ONMe<jats:sub>3<\/jats:sub> to give the triply\u2010O\u2010inserted product P(OBaz)<jats:sub>3<\/jats:sub>, an inorganic version of triphenyl phosphite; a corresponding transformation with PPh<jats:sub>3<\/jats:sub> is inconceivable. Thermodynamically, what drives these striking differences in the chemistry of PBaz<jats:sub>3<\/jats:sub> and PPh<jats:sub>3<\/jats:sub> is the great strength of the B\u2212O bond.<\/jats:p>","DOI":"10.1002\/anie.201810366","type":"journal-article","created":{"date-parts":[[2018,10,12]],"date-time":"2018-10-12T13:15:51Z","timestamp":1539350151000},"page":"15802-15806","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Inorganic Triphenylphosphine"],"prefix":"10.1002","volume":"57","author":[{"given":"Adam D.","family":"Gorman","sequence":"first","affiliation":[{"name":"School of Chemistry University of Bristol  Cantock's Close Bristol BS8 1TS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jonathan A.","family":"Bailey","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Bristol  Cantock's Close Bristol BS8 1TS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Natalie","family":"Fey","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Bristol  Cantock's Close Bristol BS8 1TS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tom A.","family":"Young","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Bristol  Cantock's Close Bristol BS8 1TS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hazel A.","family":"Sparkes","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Bristol  Cantock's Close Bristol BS8 1TS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7250-4679","authenticated-orcid":false,"given":"Paul G.","family":"Pringle","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Bristol  Cantock's Close Bristol BS8 1TS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,11,8]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19260590907"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol070328y"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C1SC00500F"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b05056"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201405627"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC00161K"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02661"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.274.5295.2107"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200903390"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200903390"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201208351"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201208351"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.5b01088"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06566"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/cmdc.201700047"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100088b"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja511766p"},{"key":"e_1_2_2_16_1","first-page":"153","volume-title":"Topics in Organometallic Chemistry, Vol.\u200549","author":"Johnson H. 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