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The reaction of (C\n                    <jats:sub>5<\/jats:sub>\n                    Me\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    Th[PH(Mes)]\n                    <jats:sub>2<\/jats:sub>\n                    , Mes=2,4,6\u2010Me\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    , with 1\u2005atm of CO yields (C\n                    <jats:sub>5<\/jats:sub>\n                    Me\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    Th(\n                    <jats:italic>\u03ba<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    \u2010(O,O)\u2010OCH\n                    <jats:sub>2<\/jats:sub>\n                    PMes\u2010C(O)PMes), in which one CO molecule is inserted into each thorium\u2013phosphorus bond. Concomitant transfer of two protons, formerly coordinated to phosphorus, are now bound to one of the carbon atoms from one of the inserted CO molecules. DFT calculations were employed to determine the lowest energy pathway. With\n                    <jats:italic>tert<\/jats:italic>\n                    \u2010butyl nitrile,\n                    <jats:sup>\n                      <jats:italic>t<\/jats:italic>\n                    <\/jats:sup>\n                    BuCN, only one nitrile inserts into a thorium\u2013phosphorus bond, but the proton is transferred to nitrogen with one phosphido remaining unperturbed affording (C\n                    <jats:sub>5<\/jats:sub>\n                    Me\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    Th[PH(Mes)][\n                    <jats:italic>\u03ba<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    \u2010(P,N)\u2010N(H)C(CMe\n                    <jats:sub>3<\/jats:sub>\n                    )P(Mes)]. Surprisingly, reaction of this compound with KN(SiMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    removes the proton bound to nitrogen, not phosphorus.\n                  <\/jats:p>","DOI":"10.1002\/anie.201810511","type":"journal-article","created":{"date-parts":[[2018,10,17]],"date-time":"2018-10-17T10:19:11Z","timestamp":1539771551000},"page":"16748-16753","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Functionalization of Carbon Monoxide and\n                    <i>tert<\/i>\n                    \u2010Butyl Nitrile by Intramolecular Proton Transfer in a Bis(Phosphido) Thorium Complex"],"prefix":"10.1002","volume":"57","author":[{"given":"Sean P.","family":"Vilanova","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Missouri  Columbia MO 65211 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