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Methanol is arguably the most desirable C<jats:sub>1<\/jats:sub> product of CO<jats:sub>2<\/jats:sub>RR, although it typically forms in negligible amounts. In our search for efficient methanol\u2010producing CO<jats:sub>2<\/jats:sub>RR catalysts, we have engineered Ag\u2010Zn catalysts by pulse\u2010depositing Zn dendrites onto Ag foams (PD\u2010Zn\/Ag foam). By themselves, Zn and Ag cannot effectively reduce CO<jats:sub>2<\/jats:sub> to CH<jats:sub>3<\/jats:sub>OH, while their alloys produce CH<jats:sub>3<\/jats:sub>OH with Faradaic efficiencies of approximately 1\u2009%. Interestingly, with nanostructuring PD\u2010Zn\/Ag foam reduces CO<jats:sub>2<\/jats:sub> to CH<jats:sub>3<\/jats:sub>OH with Faradaic efficiency and current density values reaching as high as 10.5\u2009% and \u22122.7\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup>, respectively. Control experiments and DFT calculations pinpoint strained undercoordinated Zn atoms as the active sites for CO<jats:sub>2<\/jats:sub>RR to CH<jats:sub>3<\/jats:sub>OH in a reaction pathway mediated by adsorbed CO and formaldehyde. Surprisingly, the stability of the *CHO intermediate does not influence the activity.<\/jats:p>","DOI":"10.1002\/anie.201810991","type":"journal-article","created":{"date-parts":[[2018,12,19]],"date-time":"2018-12-19T09:54:07Z","timestamp":1545213247000},"page":"2256-2260","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":150,"title":["Enhanced Electroreduction of Carbon Dioxide to Methanol Using Zinc Dendrites Pulse\u2010Deposited on Silver Foam"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7890-4024","authenticated-orcid":false,"given":"Qi Hang","family":"Low","sequence":"first","affiliation":[{"name":"Department of Chemistry Faculty of Science National University of Singapore  3 Science Drive 3 Singapore 117543 Singapore"},{"name":"Solar Energy Research Institute of Singapore, SERIS National University of Singapore (NUS)  7 Engineering Drive 1, Building E3A, #06-01 Singapore 117574 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