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Although this compound displays a contact ion\u2010pair structure, Cu<jats:sup>I<\/jats:sup>H\u2010like catalytic activity was envisaged in carbonyl hydrosilylation. Sufficient moisture stability allowed the catalysis in aqueous\/organic media. Mechanistic study further showed that a phenyl group on the borate anion is abstracted by [(IPr)Cu]<jats:sup>+<\/jats:sup> to give the cationic organocopper complex [(IPr)<jats:sub>2<\/jats:sub>Cu<jats:sub>2<\/jats:sub>(\u03bc\u2010Ph)][BPh<jats:sub>4<\/jats:sub>].<\/jats:p>","DOI":"10.1002\/anie.201811890","type":"journal-article","created":{"date-parts":[[2018,12,7]],"date-time":"2018-12-07T16:04:43Z","timestamp":1544198683000},"page":"1818-1822","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["A Masked Cuprous Hydride as a Catalyst for Carbonyl Hydrosilylation in Aqueous Solutions"],"prefix":"10.1002","volume":"58","author":[{"given":"Florian","family":"Ritter","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  Landoltweg 1 52056 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Debabrata","family":"Mukherjee","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  Landoltweg 1 52056 Aachen Germany"},{"name":"Current address: Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur West Bengal 721302 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thomas P.","family":"Spaniol","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  Landoltweg 1 52056 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Hoffmann","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  Landoltweg 1 52056 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1636-5464","authenticated-orcid":false,"given":"Jun","family":"Okuda","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  Landoltweg 1 52056 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,1,3]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00366"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.201600039"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0684321"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1080\/00304940709458641"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar7001655"},{"key":"e_1_2_2_7_2","first-page":"145","volume-title":"Prog. 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