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In the case of 1,2\u2010arylboration, the formation of a quaternary center occurred through a rare cross\u2010coupling reaction of a tertiary organometallic complex. 1,1\u2010Arylboration was enabled by catalyst optimization and occurred through a \u03b2\u2010hydride elimination\/reinsertion cascade. Enantioselective variants of both processes are presented as well as mechanistic investigations.<\/jats:p>","DOI":"10.1002\/anie.201812533","type":"journal-article","created":{"date-parts":[[2018,12,6]],"date-time":"2018-12-06T22:08:22Z","timestamp":1544134102000},"page":"1719-1723","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":114,"title":["Catalyst\u2010Controlled 1,2\u2010 and 1,1\u2010Arylboration of \u03b1\u2010Alkyl Alkenyl Arenes"],"prefix":"10.1002","volume":"58","author":[{"given":"Allison M.","family":"Bergmann","sequence":"first","affiliation":[{"name":"Department of Chemistry Indiana University  800 E. 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