{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T17:09:25Z","timestamp":1790010565460,"version":"4.0.1"},"reference-count":109,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2019,2,14]],"date-time":"2019-02-14T00:00:00Z","timestamp":1550102400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21522203"],"award-info":[{"award-number":["21522203"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21871119"],"award-info":[{"award-number":["21871119"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,3,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Heterasumanenes\n                    <jats:bold>4<\/jats:bold>\n                    \u2013\n                    <jats:bold>6<\/jats:bold>\n                    containing chalcogen (S, Se, and Te) and phosphorus atoms have been synthesized in a one\u2010pot reaction from trichalcogenasumanenes\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>3<\/jats:bold>\n                    by replacing one chalcogen atom with a P=S unit. The P=S unit makes\n                    <jats:bold>4<\/jats:bold>\n                    \u2013\n                    <jats:bold>6<\/jats:bold>\n                    almost planar and shrinks the HOMO\u2013LUMO gap as compared to\n                    <jats:bold>1<\/jats:bold>\n                    \u2013\n                    <jats:bold>3<\/jats:bold>\n                    . The bonding between Ag\n                    <jats:sup>+<\/jats:sup>\n                    and S atom on P=S brings about a distinct change to the optical properties of\n                    <jats:bold>4<\/jats:bold>\n                    \u2013\n                    <jats:bold>6<\/jats:bold>\n                    ;\n                    <jats:bold>4<\/jats:bold>\n                    in particular shows a selective fluorescence response toward Ag\n                    <jats:sup>+<\/jats:sup>\n                    with LOD of 0.21\u2005\u03bc\n                    <jats:sc>m<\/jats:sc>\n                    . Compounds\n                    <jats:bold>4<\/jats:bold>\n                    \u2013\n                    <jats:bold>6<\/jats:bold>\n                    form complexes with AgNO\n                    <jats:sub>3<\/jats:sub>\n                    to be (\n                    <jats:bold>4<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u22c5AgNO\n                    <jats:sub>3<\/jats:sub>\n                    , (\n                    <jats:bold>5<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u22c5AgNO\n                    <jats:sub>3<\/jats:sub>\n                    , and (\n                    <jats:bold>6<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u22c5(AgNO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    . In complexes, the coordination between Ag\n                    <jats:sup>+<\/jats:sup>\n                    and P=S is observed, which leads to shrinkage of C\u2212P and C\u2212X (X=S, Se, Te) bond lengths. As a result,\n                    <jats:bold>4<\/jats:bold>\n                    ,\n                    <jats:bold>5<\/jats:bold>\n                    , and\n                    <jats:bold>6<\/jats:bold>\n                    are all bowl\u2010shaped in complexes with bowl\u2010depths reaching to 0.66\u2005\u00c5, 0.42\u2005\u00c5, and 0.40\u2005\u00c5, respectively. There are Ag\u2212Te dative bonds between Ag\n                    <jats:sup>+<\/jats:sup>\n                    and Te atom on telluorophene in (\n                    <jats:bold>6<\/jats:bold>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u22c5(AgNO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/anie.201813070","type":"journal-article","created":{"date-parts":[[2019,1,24]],"date-time":"2019-01-24T10:24:06Z","timestamp":1548325446000},"page":"3819-3823","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":54,"title":["Doping Sumanene with Both Chalcogens and Phosphorus(V): One\u2010Step Synthesis, Coordination, and Selective Response Toward Ag\n                    <sup>I<\/sup>"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1598-1353","authenticated-orcid":false,"given":"Shitao","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Applied Organic Chemistry Lanzhou University  Tianshui Southern Road 222 Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chaoxian","family":"Yan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Applied Organic Chemistry Lanzhou University  Tianshui Southern Road 222 Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9031-7065","authenticated-orcid":false,"given":"Jihai","family":"Shang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Applied Organic Chemistry Lanzhou University  Tianshui Southern Road 222 Lanzhou 730000 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[11e] and:"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1055\/s-0033-1339115"},{"key":"e_1_2_2_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.201500211"},{"key":"e_1_2_2_63_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2016.06.028"},{"key":"e_1_2_2_64_1","unstructured":"Selected references for cation-\u03c0 complexes of sumanene:"},{"key":"e_1_2_2_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200702826"},{"key":"e_1_2_2_65_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200702826"},{"key":"e_1_2_2_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905567"},{"key":"e_1_2_2_66_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200905567"},{"key":"e_1_2_2_67_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1208686"},{"key":"e_1_2_2_68_1","unstructured":"For Group\u200514 element-doped sumanenes see:"},{"key":"e_1_2_2_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja906566r"},{"key":"e_1_2_2_70_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2009.11.102"},{"key":"e_1_2_2_71_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0ob00987c"},{"key":"e_1_2_2_72_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201201223"},{"key":"e_1_2_2_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b02254"},{"key":"e_1_2_2_74_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7QM00590C"},{"key":"e_1_2_2_75_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1896"},{"key":"e_1_2_2_76_1","unstructured":"For the synthesis see:"},{"key":"e_1_2_2_77_2","doi-asserted-by":"publisher","DOI":"10.1039\/a905860e"},{"key":"e_1_2_2_78_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201308781"},{"key":"e_1_2_2_78_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308781"},{"key":"e_1_2_2_79_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC08170C"},{"key":"e_1_2_2_80_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606383"},{"key":"e_1_2_2_80_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606383"},{"key":"e_1_2_2_81_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC05885C"},{"key":"e_1_2_2_82_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409620"},{"key":"e_1_2_2_82_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409620"},{"key":"e_1_2_2_83_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC09531C"},{"key":"e_1_2_2_84_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201707397"},{"key":"e_1_2_2_84_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201707397"},{"key":"e_1_2_2_85_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12119"},{"key":"e_1_2_2_86_1","unstructured":"\u00a0"},{"key":"e_1_2_2_87_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199213391"},{"key":"e_1_2_2_87_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19921041021"},{"key":"e_1_2_2_88_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)93792-5"},{"key":"e_1_2_2_89_2","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4020(79)88028-X"},{"key":"e_1_2_2_90_1","unstructured":"CCDC\u20051879008 1879009 1879010 1879011 1879012 and 1879013(4 5 6 (4)2\u22c5AgNO3 (5)2\u22c5AgNO3 and (4)2\u22c5(AgNO3)3) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge fromThe Cambridge Crystallographic Data Centre."},{"key":"e_1_2_2_91_1","doi-asserted-by":"publisher","DOI":"10.1002\/etc.5620180112"},{"key":"e_1_2_2_92_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00328D"},{"key":"e_1_2_2_93_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8QM00168E"},{"key":"e_1_2_2_94_1","unstructured":"\u00a0"},{"key":"e_1_2_2_95_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b01991"},{"key":"e_1_2_2_96_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(98)00417-4"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201813070","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201813070","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.201813070","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201813070","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,10]],"date-time":"2023-09-10T15:17:25Z","timestamp":1694359045000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201813070"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,2,14]]},"references-count":109,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2019,3,18]]}},"alternative-id":["10.1002\/anie.201813070"],"URL":"https:\/\/doi.org\/10.1002\/anie.201813070","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,2,14]]},"assertion":[{"value":"2018-11-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-02-14","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}