{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:29:06Z","timestamp":1786976946625,"version":"build-2736575974"},"reference-count":54,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2019,1,28]],"date-time":"2019-01-28T00:00:00Z","timestamp":1548633600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["EXC 314\/2"],"award-info":[{"award-number":["EXC 314\/2"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006188","name":"Einstein Stiftung Berlin","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100006188","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,3,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A straightforward gram\u2010scale preparation of cyclohexa\u20101,4\u2010diene\u2010based hydrogen cyanide (HCN) surrogates is reported. These are bench\u2010stable but formally release HCN and rearomatize when treated with Lewis acids. For BCl\n                    <jats:sub>3<\/jats:sub>\n                    , the formation of the isocyanide adduct [(CN)BCl\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    and the corresponding Wheland complex was verified by mass spectrometry. In the presence of 1,1\u2010di\u2010 and trisubstituted alkenes, transfer of HCN from the surrogate to the C\u2212C double bond occurs, affording highly substituted nitriles with Markovnikov selectivity. The success of this transfer hydrocyanation depends on the Lewis acid employed; catalytic amounts of BCl\n                    <jats:sub>3<\/jats:sub>\n                    and (C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    BCl are shown to be effective while B(C\n                    <jats:sub>6<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    and BF\n                    <jats:sub>3<\/jats:sub>\n                    \u22c5OEt\n                    <jats:sub>2<\/jats:sub>\n                    are not.\n                  <\/jats:p>","DOI":"10.1002\/anie.201813853","type":"journal-article","created":{"date-parts":[[2019,1,9]],"date-time":"2019-01-09T06:21:34Z","timestamp":1547014894000},"page":"3579-3583","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":72,"title":["Transfer Hydrocyanation of \u03b1\u2010 and \u03b1,\u03b2\u2010Substituted Styrenes Catalyzed by Boron Lewis Acids"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4463-3016","authenticated-orcid":false,"given":"Patrizio","family":"Orecchia","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie Technische Universit\u00e4t Berlin  Strasse des 17. Juni 115 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0766-960X","authenticated-orcid":false,"given":"Weiming","family":"Yuan","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Technische Universit\u00e4t Berlin  Strasse des 17. Juni 115 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1487-9218","authenticated-orcid":false,"given":"Martin","family":"Oestreich","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Technische Universit\u00e4t Berlin  Strasse des 17. Juni 115 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,1,28]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","first-page":"1","volume":"75","author":"Rajanbabu T. V.","year":"2011","journal-title":"Org. 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