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Concentrated electrolytes can improve the oxidative\/reductive stability, but encounter high viscosity. Herein, a co\u2010solvent formulation was designed to resolve the dilemma. By adding electrochemically \u201cinert\u201d dichloromethane (DCM) as a diluent in concentrated ethyl acetate (EA)\u2010based electrolyte, the co\u2010solvent electrolyte demonstrated a high ionic conductivity (0.6\u2005mS\u2009cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), low viscosity (0.35\u2005Pa\u2009s), and wide range of potential window (0\u20134.85\u2005V) at \u221270\u2009\u00b0C. Spectral characterizations and simulations show these unique properties are associated with the co\u2010solvation structure, in which high\u2010concentration clusters of salt in the EA solvent were surrounded by mobile DCM diluent. Overall, this novel electrolyte enabled rechargeable metallic Li battery with high energy (178\u2005Wh\u2009kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and power (2877\u2005W\u2009kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) at \u221270\u2009\u00b0C.\n                  <\/jats:p>","DOI":"10.1002\/anie.201900266","type":"journal-article","created":{"date-parts":[[2019,3,1]],"date-time":"2019-03-01T06:27:50Z","timestamp":1551421670000},"page":"5623-5627","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":320,"title":["High\u2010Energy Rechargeable Metallic Lithium Battery at \u221270\u2009\u00b0C Enabled by a Cosolvent Electrolyte"],"prefix":"10.1002","volume":"58","author":[{"given":"Xiaoli","family":"Dong","sequence":"first","affiliation":[{"name":"Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuxiao","family":"Lin","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering and Materials Science Michigan State University  East Lansing MI 48824 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Panlong","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanyuan","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianhang","family":"Huang","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Duan","family":"Bin","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Fudan University  Shanghai 200433 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