{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T19:18:18Z","timestamp":1790018298363,"version":"4.0.1"},"reference-count":74,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2019,3,12]],"date-time":"2019-03-12T00:00:00Z","timestamp":1552348800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100004807","name":"California Department of Fish and Game","doi-asserted-by":"publisher","award":["grant Mi477\/31-1"],"award-info":[{"award-number":["grant Mi477\/31-1"]}],"id":[{"id":"10.13039\/100004807","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The geminal frustrated Lewis pair (FLP) (F<jats:sub>5<\/jats:sub>C<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>SnCH<jats:sub>2<\/jats:sub>P(tBu)<jats:sub>2<\/jats:sub> (<jats:bold>2<\/jats:bold>) was prepared by reacting (F<jats:sub>5<\/jats:sub>C<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>SnCl with LiCH<jats:sub>2<\/jats:sub>P(tBu)<jats:sub>2<\/jats:sub>. It is neutral and contains an extremely electronegatively substituted, but relatively soft (hard\u2013soft acid\u2013base, HSAB) acidic tin function. Its FLP\u2010type reactivity was proven by reaction with a variety of small molecules (CO<jats:sub>2<\/jats:sub>, SO<jats:sub>2<\/jats:sub>, CS<jats:sub>2<\/jats:sub>, PhNCO, HCl, (Ph<jats:sub>3<\/jats:sub>P)AuCl). However, it shows no reaction in H\/D scrambling experiments with H<jats:sub>2<\/jats:sub>\/D<jats:sub>2<\/jats:sub> mixtures and binds CO<jats:sub>2<\/jats:sub> reversibly, as was observed by VT\u2010NMR spectroscopy. Compound <jats:bold>2<\/jats:bold> and all its adducts were completely characterized by means of multinuclear NMR spectroscopy, elemental analysis, and X\u2010ray diffraction experiments.<\/jats:p>","DOI":"10.1002\/anie.201901037","type":"journal-article","created":{"date-parts":[[2019,2,13]],"date-time":"2019-02-13T18:02:03Z","timestamp":1550080923000},"page":"5114-5118","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":76,"title":["A Neutral Geminal Tin\/Phosphorus Frustrated Lewis Pair"],"prefix":"10.1002","volume":"58","author":[{"given":"Philipp","family":"Holtkamp","sequence":"first","affiliation":[{"name":"Lehrstuhl f\u00fcr Anorganische Chemie und Strukturchemie, and Centrum f\u00fcr Molekulare Materialien CM<sub>2<\/sub> Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Felix","family":"Friedrich","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Anorganische Chemie und Strukturchemie, and Centrum f\u00fcr Molekulare Materialien CM<sub>2<\/sub> Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Erik","family":"Stratmann","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Anorganische Chemie und Strukturchemie, and Centrum f\u00fcr Molekulare Materialien CM<sub>2<\/sub> Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas","family":"Mix","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Anorganische Chemie und Strukturchemie, and Centrum f\u00fcr Molekulare Materialien CM<sub>2<\/sub> Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beate","family":"Neumann","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Anorganische Chemie und Strukturchemie, and Centrum f\u00fcr Molekulare Materialien CM<sub>2<\/sub> Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hans\u2010Georg","family":"Stammler","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Anorganische Chemie und Strukturchemie, and Centrum f\u00fcr Molekulare Materialien CM<sub>2<\/sub> Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3271-5217","authenticated-orcid":false,"given":"Norbert W.","family":"Mitzel","sequence":"additional","affiliation":[{"name":"Lehrstuhl f\u00fcr Anorganische Chemie und Strukturchemie, and Centrum f\u00fcr Molekulare Materialien CM<sub>2<\/sub> Fakult\u00e4t f\u00fcr Chemie Universit\u00e4t Bielefeld  Universit\u00e4tsstra\u00dfe 25 33615 Bielefeld Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,3,12]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaf7229"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar500375j"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409800"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409800"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC00395K"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200903708"},{"key":"e_1_2_2_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200903708"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/b819621d"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901636"},{"key":"e_1_2_2_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200901636"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/b710475h"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja067961j"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1134230"},{"key":"e_1_2_2_12_1","volume-title":"Valence and the Structure of Atoms and Molecules","author":"Lewis G. 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