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The reactivity of this complex demonstrates the ability of the cluster\u2010templating ligand to produce a well\u2010defined polynuclear transition metal cluster that can access distinct single\u2010site and cooperative reactivity controlled by either substrate steric demands or reaction media.<\/jats:p>","DOI":"10.1002\/anie.201901599","type":"journal-article","created":{"date-parts":[[2019,3,4]],"date-time":"2019-03-04T02:56:22Z","timestamp":1551668182000},"page":"5687-5691","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Ligand\u2010Based Control of Single\u2010Site vs. Multi\u2010Site Reactivity by a Trichromium Cluster"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2092-1718","authenticated-orcid":false,"given":"Amymarie K.","family":"Bartholomew","sequence":"first","affiliation":[{"name":"Department of Chemistry Columbia University  New York NY 10027 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cristin E.","family":"Juda","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology Harvard University  12 Oxford St. Cambridge MA 02138 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonathon N.","family":"Nessralla","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of California, Berkeley  Berkeley CA 94720 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Benjamin","family":"Lin","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology Harvard University  12 Oxford St. Cambridge MA 02138 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"SuYin Grass","family":"Wang","sequence":"additional","affiliation":[{"name":"ChemMatCARS Beamline The University of Chicago Advanced Photon Source  Argonne IL 60429 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Sheng","family":"Chen","sequence":"additional","affiliation":[{"name":"ChemMatCARS Beamline The University of Chicago Advanced Photon Source  Argonne IL 60429 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5946-9629","authenticated-orcid":false,"given":"Theodore A.","family":"Betley","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology Harvard University  12 Oxford St. Cambridge MA 02138 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,3,27]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1073877"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400641x"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1061500"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr400461p"},{"key":"e_1_2_2_6_1","unstructured":"\u00a0"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi034595x"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/b107336b"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2007.05.007"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/bi00009a008"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.275.15.11459"},{"key":"e_1_2_2_12_1","unstructured":"\u00a0"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.7554\/eLife.39451"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1256679"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aar2765"},{"key":"e_1_2_2_16_1","unstructured":"\u00a0"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b01445"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b01962"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b06426"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409676"},{"key":"e_1_2_2_20_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409676"},{"key":"e_1_2_2_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr4004067"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja503629r"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04738"},{"key":"e_1_2_2_24_1","volume-title":"Metal Clusters in Chemistry, Vol.\u20051","year":"1999"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic501490e"},{"key":"e_1_2_2_26_1","unstructured":"CCDC\u20051895532 1895533 and 1895569\u20131895577 contain the supplementary crystallographic data for this paper. 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