{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T23:12:57Z","timestamp":1790550777973,"version":"4.1.0"},"reference-count":107,"publisher":"Wiley","issue":"24","license":[{"start":{"date-parts":[[2019,5,15]],"date-time":"2019-05-15T00:00:00Z","timestamp":1557878400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100005156","name":"Alexander von Humboldt-Stiftung","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100005156","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006188","name":"Einstein Stiftung Berlin","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100006188","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,6,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    An efficient synthesis of functionalized tertiary \u03b1\u2010silyl alcohols by an enantio\u2010 and diastereoselective copper\u2010catalyzed three\u2010component coupling of 1,3\u2010dienes, bis(pinacolato)diboron, and acylsilanes is reported. The reaction proceeds well with different 1,3\u2010dienes and a broad range of aryl\u2010 as well as alkenyl\u2010 but also alkyl\u2010substituted acylsilanes. The target compounds are formed with high regio\u2010, diastereo\u2010, and enantioselectivity (up to 99\u2009%\n                    <jats:italic>ee<\/jats:italic>\n                    and d.r. &gt;20:1) and are highly versatile synthetic building blocks.\n                  <\/jats:p>","DOI":"10.1002\/anie.201903174","type":"journal-article","created":{"date-parts":[[2019,4,4]],"date-time":"2019-04-04T13:05:48Z","timestamp":1554383148000},"page":"8211-8215","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":86,"title":["Tertiary \u03b1\u2010Silyl Alcohols by Diastereoselective Coupling of 1,3\u2010Dienes and Acylsilanes Initiated by Enantioselective Copper\u2010Catalyzed Borylation"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6094-3268","authenticated-orcid":false,"given":"Jian\u2010Jun","family":"Feng","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie Technische Universit\u00e4t Berlin  Strasse des 17. Juni 115 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1487-9218","authenticated-orcid":false,"given":"Martin","family":"Oestreich","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Chemie Technische Universit\u00e4t Berlin  Strasse des 17. Juni 115 10623 Berlin Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,5,15]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/3527602607.ch10"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar300200h"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm3010114"},{"key":"e_1_2_2_5_1","unstructured":"For authoritative reviews see:"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201800585"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(00)01089-9"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar50075a003"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500715t"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b11495"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704696"},{"key":"e_1_2_2_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704696"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol1006532"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209020"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209020"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol051559c"},{"key":"e_1_2_2_16_1","unstructured":"For authoritative reviews on acylsilane chemistry see:"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60185d"},{"key":"e_1_2_2_18_2","first-page":"1","volume-title":"Science of Synthesis Knowledge Updates 2012\/2","author":"Garrett M. 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