{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T03:51:02Z","timestamp":1793332262685,"version":"4.5.0"},"reference-count":77,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2019,5,2]],"date-time":"2019-05-02T00:00:00Z","timestamp":1556755200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"NSERC of Canada","award":["RGPIN-2018-05574"],"award-info":[{"award-number":["RGPIN-2018-05574"]}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,6,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Reaction of a tethered triamine ligand with Bi(NMe\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    gives a Bi triamide, for which a Bi\n                    <jats:sup>I<\/jats:sup>\n                    electronic structure is shown to be most appropriate. The T\u2010shaped geometry at bismuth provides the first structural model for edge inversion in bismuthines and the only example of a planar geometry for pnictogen triamides. Analogous phosphorus compounds exhibit a distorted pyramidal geometry because of different Bi\u2212N and P\u2212N bond polarities. Although considerable Bi\n                    <jats:sup>I<\/jats:sup>\n                    character is indicated for the title Bi triamide, it exhibits reactivity similar to Bi\n                    <jats:sup>III<\/jats:sup>\n                    electrophiles, and expresses either a vacant or a filled p orbital at Bi, as evidenced by coordination of either pyridine\n                    <jats:italic>N<\/jats:italic>\n                    \u2010oxide or W(CO)\n                    <jats:sub>5<\/jats:sub>\n                    . The product of the former shows evidence of coordination\u2010induced oxidation state change at bismuth.\n                  <\/jats:p>","DOI":"10.1002\/anie.201903354","type":"journal-article","created":{"date-parts":[[2019,4,3]],"date-time":"2019-04-03T21:52:43Z","timestamp":1554328363000},"page":"7850-7855","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":105,"title":["A Redox\u2010Confused Bismuth(I\/III) Triamide with a T\u2010Shaped Planar Ground State"],"prefix":"10.1002","volume":"58","author":[{"given":"Marcus B.","family":"Kindervater","sequence":"first","affiliation":[{"name":"Chemistry Department Dalhousie University  6274 Coburg Road Halifax Nova Scotia Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4356-6795","authenticated-orcid":false,"given":"Katherine M.","family":"Marczenko","sequence":"additional","affiliation":[{"name":"Chemistry Department Dalhousie 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