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Questions arise relating to the prebiotic availability of DAP and other amidophosphosphorus species on the early earth. Herein, we demonstrate that DAP and other amino\u2010derivatives of phosphates\/phosphite are generated when Fe<jats:sub>3<\/jats:sub>P (proxy for mineral schreibersite), condensed phosphates, and reduced oxidation state phosphorus compounds, which could have been available on early earth, are exposed to aqueous ammonia solutions. DAP is shown to remain in aqueous solution under conditions where phosphate is precipitated out by divalent metals. These results show that nitrogenated analogues of phosphate and reduced phosphite species can be produced and remain in solution, overcoming the thermodynamic barrier for phosphorylation in water, increasing the possibility that abiotic phosphorylation reactions occurred in aqueous environments on early earth.<\/jats:p>","DOI":"10.1002\/anie.201903808","type":"journal-article","created":{"date-parts":[[2019,4,16]],"date-time":"2019-04-16T05:15:17Z","timestamp":1555391717000},"page":"8151-8155","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":60,"title":["Geochemical Sources and Availability of Amidophosphates on the Early Earth"],"prefix":"10.1002","volume":"58","author":[{"given":"Cl\u00e9mentine","family":"Gibard","sequence":"first","affiliation":[{"name":"Department of Chemistry The Scripps Research Institute  10550 North Torrey Pines Road La Jolla CA 92037 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ian B.","family":"Gorrell","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Leeds  Woodhouse Lane Leeds LS2 9JT UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eddy I.","family":"Jim\u00e9nez","sequence":"additional","affiliation":[{"name":"Department of Chemistry The Scripps Research Institute  10550 North Torrey Pines Road La Jolla CA 92037 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Terence P.","family":"Kee","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Leeds  Woodhouse Lane Leeds LS2 9JT UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthew A.","family":"Pasek","sequence":"additional","affiliation":[{"name":"School of Geosciences University of South Florida  Tampa FL 33620 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5238-610X","authenticated-orcid":false,"given":"Ramanarayanan","family":"Krishnamurthy","sequence":"additional","affiliation":[{"name":"Department of Chemistry The Scripps Research Institute  10550 North Torrey Pines Road La Jolla CA 92037 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,5,8]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1007\/978-3-642-21625-1_3","volume-title":"Origins of Life: The Primal Self-Organization","author":"Pasek M. 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