{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T06:27:03Z","timestamp":1790922423650,"version":"4.1.0"},"reference-count":75,"publisher":"Wiley","issue":"25","license":[{"start":{"date-parts":[[2019,5,10]],"date-time":"2019-05-10T00:00:00Z","timestamp":1557446400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004281","name":"Narodowe Centrum Nauki","doi-asserted-by":"publisher","award":["Grant OPUS DEC-2017\/27\/B\/ST5\/02329"],"award-info":[{"award-number":["Grant OPUS DEC-2017\/27\/B\/ST5\/02329"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001870","name":"Fundacja na rzecz Nauki Polskiej","doi-asserted-by":"publisher","award":["VENTURES\/2011-7\/6"],"award-info":[{"award-number":["VENTURES\/2011-7\/6"]}],"id":[{"id":"10.13039\/501100001870","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,6,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Over the past 150\u2005years, a certain mythology has arisen around the mechanistic pathways of the oxygenation of organometallics with non\u2010redox\u2010active metal centers as well as the character of products formed. Notably, there is a widespread perception that the formation of commonly encountered metal alkoxide species results from the auto\u2010oxidation reaction, in which a parent metal alkyl compound is oxidized by the metal alkylperoxide via oxygen transfer reaction. Now, harnessing a well\u2010defined zinc ethylperoxide incorporating a \u03b2\u2010diketiminate ligand, the investigated alkylperoxide compounds do not react with the parent metal alkyl complex as well as Et<jats:sub>2<\/jats:sub>Zn to form a zinc alkoxide. Upon treatment of the zinc ethylperoxide with Et<jats:sub>2<\/jats:sub>Zn, a previously unobserved ligand exchange process is favored. Isolation of a zinc hydroxide carboxylate as a product of decomposition of the parent zinc ethylperoxide demonstrates the susceptibility of the latter to O\u2212O bond homolysis.<\/jats:p>","DOI":"10.1002\/anie.201904380","type":"journal-article","created":{"date-parts":[[2019,4,12]],"date-time":"2019-04-12T14:33:24Z","timestamp":1555079604000},"page":"8526-8530","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["An In\u2010Depth Look at the Reactivity of Non\u2010Redox\u2010Metal Alkylperoxides"],"prefix":"10.1002","volume":"58","author":[{"given":"Tomasz","family":"Pietrzak","sequence":"first","affiliation":[{"name":"Faculty of Chemistry Warsaw University of Technology  Noakowskiego 3 00-664 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Iwona","family":"Justyniak","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry Polish Academy of Science  Kasprzaka 44\/52 01-224 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcin","family":"Kubisiak","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Warsaw University of Technology  Noakowskiego 3 00-664 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Emil","family":"Bojarski","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Warsaw University of Technology  Noakowskiego 3 00-664 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3407-0395","authenticated-orcid":false,"given":"Janusz","family":"Lewi\u0144ski","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Warsaw University of Technology  Noakowskiego 3 00-664 Warsaw Poland"},{"name":"Institute of Physical Chemistry Polish Academy of Science  Kasprzaka 44\/52 01-224 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,5,10]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60243a003"},{"key":"e_1_2_2_2_1","doi-asserted-by":"crossref","first-page":"807","DOI":"10.1002\/9780470771730.ch23","volume-title":"Peroxides","author":"Brindley P. B.","year":"1983"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00093a001"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00538a077"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/b001780i"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr0406458"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05251"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00636"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08678"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200804402"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200804402"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9720523"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja308915x"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00070a041"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja028500a"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr020633r"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar2003072"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00260"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199617251"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19961081530"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199704101"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971090414"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200351940"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200351940"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/om400830e"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201603931"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201500764"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC00600G"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.18490710205"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/j29680001074"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.19960020521"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201704758"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200305053"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201805180"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja036020t"},{"key":"e_1_2_2_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201200448"},{"key":"e_1_2_2_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201200448"},{"key":"e_1_2_2_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja961083f"},{"key":"e_1_2_2_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00206a056"},{"key":"e_1_2_2_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(00)83205-2"},{"key":"e_1_2_2_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2017.12.039"},{"key":"e_1_2_2_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200900746"},{"key":"e_1_2_2_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200900449"},{"key":"e_1_2_2_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201000520"},{"key":"e_1_2_2_39_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201000520"},{"key":"e_1_2_2_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511590"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201511590"},{"key":"e_1_2_2_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.7b00287"},{"key":"e_1_2_2_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00286a044"},{"key":"e_1_2_2_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja010165n"},{"key":"e_1_2_2_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic0607787"},{"key":"e_1_2_2_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201500141"},{"key":"e_1_2_2_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201500141"},{"key":"e_1_2_2_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC04644K"},{"key":"e_1_2_2_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12434"},{"key":"e_1_2_2_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609526"},{"key":"e_1_2_2_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201609526"},{"key":"e_1_2_2_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703125"},{"key":"e_1_2_2_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200703125"},{"key":"e_1_2_2_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200803254"},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200803254"},{"key":"e_1_2_2_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200902716"},{"key":"e_1_2_2_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200902716"},{"key":"e_1_2_2_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201700503"},{"key":"e_1_2_2_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic048336n"},{"key":"e_1_2_2_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic0600230"},{"key":"e_1_2_2_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic062438r"},{"key":"e_1_2_2_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja992678o"},{"key":"e_1_2_2_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja003850n"},{"key":"e_1_2_2_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/om010301x"},{"key":"e_1_2_2_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200300075"},{"key":"e_1_2_2_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200601001"},{"key":"e_1_2_2_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200601001"},{"key":"e_1_2_2_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201403851"},{"key":"e_1_2_2_62_1","unstructured":"CCDC\u20051890955\u20131890959contain the supplementary crystallographic data for this paper. These data are provided free of charge byThe Cambridge Crystallographic Data Centre."}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201904380","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201904380","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.201904380","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201904380","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,9]],"date-time":"2023-09-09T15:40:55Z","timestamp":1694274055000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201904380"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,5,10]]},"references-count":75,"journal-issue":{"issue":"25","published-print":{"date-parts":[[2019,6,17]]}},"alternative-id":["10.1002\/anie.201904380"],"URL":"https:\/\/doi.org\/10.1002\/anie.201904380","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,5,10]]},"assertion":[{"value":"2019-04-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-05-10","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}