{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:29:44Z","timestamp":1786976984747,"version":"build-2736575974"},"reference-count":63,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2019,7,3]],"date-time":"2019-07-03T00:00:00Z","timestamp":1562112000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["GM074785"],"award-info":[{"award-number":["GM074785"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["GM28962"],"award-info":[{"award-number":["GM28962"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,8,5]]},"abstract":"Abstract<\/jats:title>\n \n We report the formation of a new copper peroxynitrite (\n PN<\/jats:bold>\n ) complex [Cu\n II<\/jats:sup>\n (TMG\n 3<\/jats:sub>\n tren)(\u03ba\n 1<\/jats:sup>\n \u2010OONO)]\n +<\/jats:sup>\n (\n PN1<\/jats:bold>\n ) from the reaction of [Cu\n II<\/jats:sup>\n (TMG\n 3<\/jats:sub>\n tren)(O\n 2<\/jats:sub>\n .\u2212<\/jats:sup>\n )]\n +<\/jats:sup>\n (\n 1<\/jats:bold>\n ) with NO\n .<\/jats:sup>\n (g)<\/jats:sub>\n at \u2212125\u2009\u00b0C. The first resonance Raman spectroscopic characterization of such a metal\u2010bound\n PN<\/jats:bold>\n moiety supports a\n cis<\/jats:italic>\n \u03ba\n 1<\/jats:sup>\n \u2010(\n \u2212<\/jats:sup>\n OONO) geometry.\n PN1<\/jats:bold>\n transforms thermally into an isomeric form (\n PN2<\/jats:bold>\n ) with \u03ba\n 2<\/jats:sup>\n \u2010O,O\u2032\u2010(\n \u2212<\/jats:sup>\n OONO) coordination, which undergoes O\u2212O bond homolysis to generate a putative cupryl (LCu\n II<\/jats:sup>\n \u2212O\n .<\/jats:sup>\n ) intermediate and NO\n 2<\/jats:sub>\n .<\/jats:sup>\n . These transient species do not recombine to give a nitrato (NO\n 3<\/jats:sub>\n \u2212<\/jats:sup>\n ) product but instead proceed to effect oxidative chemistry and formation of a Cu\n II<\/jats:sup>\n \u2013nitrito (NO\n 2<\/jats:sub>\n \u2212<\/jats:sup>\n ) complex (\n 2<\/jats:bold>\n ).\n <\/jats:p>","DOI":"10.1002\/anie.201904672","type":"journal-article","created":{"date-parts":[[2019,6,3]],"date-time":"2019-06-03T15:49:39Z","timestamp":1559576979000},"page":"10936-10940","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O\n 2<\/sub>\n and NO and Mechanistic Insights into Metal\u2010Mediated Peroxynitrite Decomposition"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2147-6449","authenticated-orcid":false,"given":"Jeffrey J.","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemistry Johns Hopkins University Baltimore MD 21218 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4165-7810","authenticated-orcid":false,"given":"Maxime A.","family":"Siegler","sequence":"additional","affiliation":[{"name":"Department of Chemistry Johns Hopkins University Baltimore MD 21218 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5675-7040","authenticated-orcid":false,"given":"Kenneth D.","family":"Karlin","sequence":"additional","affiliation":[{"name":"Department of Chemistry Johns Hopkins University Baltimore MD 21218 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7684-7617","authenticated-orcid":false,"given":"Pierre","family":"Mo\u00ebnne\u2010Loccoz","sequence":"additional","affiliation":[{"name":"Department of Biochemistry and Molecular Biology Oregon Health & Science University Portland OR 97239 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,7,3]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.pa.30.040190.002535"},{"key":"e_1_2_2_2_1","doi-asserted-by":"crossref","first-page":"111","DOI":"10.1016\/B978-012435555-2\/50004-8","volume-title":"Nitric Oxide Principles and Actions","author":"Ignarro L. 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