{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:03:13Z","timestamp":1792782193814,"version":"4.5.0"},"reference-count":81,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2019,7,17]],"date-time":"2019-07-17T00:00:00Z","timestamp":1563321600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Theodore-von-K\u00e1rm\u00e1n-Fellowship","award":["1"],"award-info":[{"award-number":["1"]}]},{"name":"Distinguished Professorship Program funded by the Excellence Initiative of the German Federal and State Governments","award":["1"],"award-info":[{"award-number":["1"]}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,9,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A mechanochemical synthesis of one\u2010dimensional carbon allotrope carbyne model compounds, namely tetraaryl[\n                    <jats:italic>n<\/jats:italic>\n                    ]cumulenes (\n                    <jats:italic>n<\/jats:italic>\n                    =3, 5) was realized. Central for the mechanosynthesis of the cumulenic carbon nanostructures were the development of a mechanochemical Favorskii alkynylation\u2010type reaction and the implementation of a solvent\u2010free, acid\u2010free reductive elimination with tin(II) chloride by ball milling.\n                  <\/jats:p>","DOI":"10.1002\/anie.201905670","type":"journal-article","created":{"date-parts":[[2019,7,2]],"date-time":"2019-07-02T10:55:10Z","timestamp":1562064910000},"page":"12945-12949","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":60,"title":["Mechanosynthesis of Odd\u2010Numbered Tetraaryl[\n                    <i>n<\/i>\n                    ]cumulenes"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5801-5534","authenticated-orcid":false,"given":"Karen J.","family":"Ardila\u2010Fierro","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University Landoltweg 1 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9415-9917","authenticated-orcid":false,"given":"Carsten","family":"Bolm","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University Landoltweg 1 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9064-4456","authenticated-orcid":false,"given":"Jos\u00e9 G.","family":"Hern\u00e1ndez","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University Landoltweg 1 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,7,17]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"For selected recent reviews and examples see:"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201810902"},{"key":"e_1_2_2_2_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201810902"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00813A"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-07957-6"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2018.08.001"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b01716"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201800113"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7GC03797J"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC04971H"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT03866A"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs35468g"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60052a"},{"key":"e_1_2_2_13_1","unstructured":"\u00a0"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.6b02887"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.6b00277"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-019-0094-2"},{"key":"e_1_2_2_17_2","first-page":"10","author":"Budny-Godlewski K.","journal-title":"Chem. Sci."},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805505"},{"key":"e_1_2_2_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201805505"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201810141"},{"key":"e_1_2_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201810141"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805998"},{"key":"e_1_2_2_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201805998"},{"key":"e_1_2_2_21_1","unstructured":"\u00a0"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1038\/42439"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs35494f"},{"key":"e_1_2_2_24_1","unstructured":"\u00a0"},{"key":"e_1_2_2_25_2","doi-asserted-by":"publisher","DOI":"10.1038\/nprot.2017.142"},{"key":"e_1_2_2_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8GC01162A"},{"key":"e_1_2_2_27_1","unstructured":"\u00a0"},{"key":"e_1_2_2_28_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1116897109"},{"key":"e_1_2_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja3091643"},{"key":"e_1_2_2_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.coche.2016.01.003"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC01993B"},{"key":"e_1_2_2_32_1","unstructured":"\u00a0"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.828"},{"key":"e_1_2_2_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00022F"},{"key":"e_1_2_2_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901228"},{"key":"e_1_2_2_35_3","doi-asserted-by":"crossref","first-page":"8466","DOI":"10.1002\/ange.201901228","volume":"131","year":"2019","journal-title":"Angew. Chem."},{"key":"e_1_2_2_36_1","unstructured":"For recent review articles see:"},{"key":"e_1_2_2_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200239h"},{"key":"e_1_2_2_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.7b00164"},{"key":"e_1_2_2_39_1","unstructured":"For recent reviews on application of CaC2as a surrogate of acetylene in chemical synthesis see:"},{"key":"e_1_2_2_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201802412"},{"key":"e_1_2_2_41_2","doi-asserted-by":"publisher","DOI":"10.3390\/molecules23102442"},{"key":"e_1_2_2_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201501323"},{"key":"e_1_2_2_43_1","unstructured":"\u00a0"},{"key":"e_1_2_2_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.5b01219"},{"key":"e_1_2_2_45_1","doi-asserted-by":"publisher","DOI":"10.15227\/orgsyn.032.0070"},{"key":"e_1_2_2_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC10155H"},{"key":"e_1_2_2_47_1","unstructured":"\u00a0"},{"key":"e_1_2_2_48_2","first-page":"1359","volume-title":"March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure","author":"Smith M. B.","year":"2007"},{"key":"e_1_2_2_49_2","first-page":"652","volume":"32","author":"Favorskii A. E.","year":"1900","journal-title":"Zh. Russ. Khim. O-va."},{"key":"e_1_2_2_50_2","doi-asserted-by":"publisher","DOI":"10.1134\/S1070428013010028"},{"key":"e_1_2_2_51_1","unstructured":"2\u2009aand3\u2009awere obtained concomitantly with formation of by-products from a background reaction between1\u2009aand KOH."},{"key":"e_1_2_2_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tca.2004.11.004"},{"key":"e_1_2_2_53_1","unstructured":"For selected examples see:"},{"key":"e_1_2_2_54_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812283"},{"key":"e_1_2_2_54_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201812283"},{"key":"e_1_2_2_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201703903"},{"key":"e_1_2_2_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802137"},{"key":"e_1_2_2_56_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201802137"},{"key":"e_1_2_2_57_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.78.2188"},{"key":"e_1_2_2_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201700168"},{"key":"e_1_2_2_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406650"},{"key":"e_1_2_2_60_1","unstructured":"\u00a0"},{"key":"e_1_2_2_61_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.44.1050"},{"key":"e_1_2_2_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200600905"},{"key":"e_1_2_2_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo01300a007"},{"key":"e_1_2_2_64_1","unstructured":"\u00a0"},{"key":"e_1_2_2_65_2","doi-asserted-by":"publisher","DOI":"10.1107\/S160053681000629X"},{"key":"e_1_2_2_66_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC00386F"},{"key":"e_1_2_2_67_1","unstructured":"Reductive elimination of2\u2009husing SnCl2in Et2O-HCl has been reported to fail leading instead to the formation of a pyridylquinolizinone derivative:"},{"key":"e_1_2_2_68_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39750000885"},{"key":"e_1_2_2_69_1","unstructured":"For reports on mechanochemical oxidative couplings of terminal acetylenes see:"},{"key":"e_1_2_2_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201100604"},{"key":"e_1_2_2_71_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3GC41847B"},{"key":"e_1_2_2_72_1","unstructured":"\u00a0"},{"key":"e_1_2_2_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b13610"},{"key":"e_1_2_2_74_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9NR01019J"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201905670","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201905670","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.201905670","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201905670","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,17]],"date-time":"2023-09-17T18:49:26Z","timestamp":1694976566000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201905670"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,7,17]]},"references-count":81,"journal-issue":{"issue":"37","published-print":{"date-parts":[[2019,9,9]]}},"alternative-id":["10.1002\/anie.201905670"],"URL":"https:\/\/doi.org\/10.1002\/anie.201905670","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,7,17]]},"assertion":[{"value":"2019-05-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-07-17","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}