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The robust method leverages the privileged reactivity of alcohols bearing electronegative hetero\u2010 atoms (O, F, N, Cl) in the \u03b2\u2010position. The reaction tolerates over 20 unique functional groups and is demonstrated on a 15\u2005mmol scale under air. Steric constraints of the catalyst allow for chemoselective amidation of primary amines in the presence of secondary amines. All catalyst components are commercially available, and the reaction proceeds under mild conditions with retention of stereocenters in both reaction partners, while producing only water as a by\u2010product.<\/jats:p>","DOI":"10.1002\/anie.201906130","type":"journal-article","created":{"date-parts":[[2019,6,17]],"date-time":"2019-06-17T18:53:15Z","timestamp":1560797595000},"page":"12211-12215","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Oxidative Amide Coupling from Functionally Diverse Alcohols and Amines Using Aerobic Copper\/Nitroxyl Catalysis"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9199-8894","authenticated-orcid":false,"given":"Paige E.","family":"Piszel","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Wisconsin-Madison  Madison WI 53706 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