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For sake of comparison, isostructural Mg\u2013Al and Zn\u2013Al analogues of these complexes, viz. [(<jats:sup>Dip<\/jats:sup>Nacnac)(X)Al\u2010M(X)(tmeda)] (M=Mg or Zn, X=I or Br) have been prepared and structurally characterized. DFT calculations reveal all compounds to have high s\u2010character metal\u2013metal bonds, the polarity of which is consistent with the electronegativities of the metals involved. Preliminary reactivity studies of [(<jats:sup>Dip<\/jats:sup>Nacnac)(Br)Al\u2010Be(Br)(tmeda)] are reported.<\/jats:p>","DOI":"10.1002\/anie.201906609","type":"journal-article","created":{"date-parts":[[2019,6,17]],"date-time":"2019-06-17T16:24:17Z","timestamp":1560788657000},"page":"11459-11463","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":86,"title":["Diagonally Related s\u2010 and p\u2010Block Metals Join Forces: Synthesis and Characterization of Complexes with Covalent Beryllium\u2013Aluminum Bonds"],"prefix":"10.1002","volume":"58","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0309-0075","authenticated-orcid":false,"given":"Albert","family":"Paparo","sequence":"first","affiliation":[{"name":"School of Chemistry Monash University PO Box 23 Clayton VIC 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cory D.","family":"Smith","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University PO Box 23 Clayton VIC 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7269-1045","authenticated-orcid":false,"given":"Cameron","family":"Jones","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University PO Box 23 Clayton VIC 3800 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,7,10]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"Selected reviews:"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100133q"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900375g"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470669266"},{"key":"e_1_2_2_5_1","unstructured":"Selected reviews:"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201800963"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00572"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00649G"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1SC00757B"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar2000875"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100216y"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0SC00388C"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature08634"},{"key":"e_1_2_2_14_1","unstructured":"\u00a0"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0059"},{"key":"e_1_2_2_16_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-36270-5_3"},{"key":"e_1_2_2_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201604362"},{"key":"e_1_2_2_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201604362"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja808524y"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2542"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201900458"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201801800"},{"key":"e_1_2_2_22_1","author":"Buchner M. 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