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A mild pathway is now reported for the quantitative conversion of hydrosilanes to silyl chlorides under visible\u2010light irradiation using neutral eosin\u2005Y as a hydrogen\u2010atom\u2010transfer photocatalyst and dichloromethane as a chlorinating agent. Stepwise chlorination of di\u2010 and trihydrosilanes was achieved in a highly selective fashion assisted by continuous\u2010flow micro\u2010tubing reactors. 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