{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T14:17:42Z","timestamp":1791728262639,"version":"4.3.4"},"reference-count":31,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2019,9,25]],"date-time":"2019-09-25T00:00:00Z","timestamp":1569369600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001665","name":"Agence Nationale de la Recherche","doi-asserted-by":"publisher","award":["ANR-16-CE05-0010-01"],"award-info":[{"award-number":["ANR-16-CE05-0010-01"]}],"id":[{"id":"10.13039\/501100001665","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2019,11,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    into valuable molecules is a field of intensive investigation with the aim of developing scalable technologies for making fuels using renewable energy sources. While electrochemical reduction into CO and formate are approaching industrial maturity, a current challenge is obtaining more reduced products like methanol. However, literature on the matter is scarce, and even more for the use of molecular catalysts. Here, we demonstrate that cobalt phthalocyanine, a well\u2010known catalyst for the electrochemical conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    to CO, can also catalyze the reaction from CO\n                    <jats:sub>2<\/jats:sub>\n                    or CO to methanol in aqueous electrolytes at ambient conditions of temperature and pressure. The studies identify formaldehyde as a key intermediate and an unexpected pH effect on selectivity. This paves the way for establishing a sequential process where CO\n                    <jats:sub>2<\/jats:sub>\n                    is first converted to CO which is subsequently used as a reactant to produce methanol. Under ideal conditions, the reaction shows a global Faradaic efficiency of 19.5\u2009% and chemical selectivity of 7.5\u2009%.\n                  <\/jats:p>","DOI":"10.1002\/anie.201909257","type":"journal-article","created":{"date-parts":[[2019,9,9]],"date-time":"2019-09-09T02:04:10Z","timestamp":1567994650000},"page":"16172-16176","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":276,"title":["Aqueous Electrochemical Reduction of Carbon Dioxide and Carbon Monoxide into Methanol with Cobalt Phthalocyanine"],"prefix":"10.1002","volume":"58","author":[{"given":"Etienne","family":"Boutin","sequence":"first","affiliation":[{"name":"Universit\u00e9 de Paris Laboratoire d'Electrochimie Mol\u00e9culaire CNRS  75013 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Min","family":"Wang","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Paris Laboratoire d'Electrochimie Mol\u00e9culaire CNRS  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Catalysis Department of Chemical Engineering Stanford University  Stanford CA 94305 USA"},{"name":"SUNCAT Center for Interface Science and Catalysis SLAC National Accelerator Laboratory  2575 Sand Hill Road Menlo Park CA 94025 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7042-4106","authenticated-orcid":false,"given":"Marc","family":"Robert","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Paris Laboratoire d'Electrochimie Mol\u00e9culaire CNRS  75013 Paris 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