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A chiral organotin compound with 3,4,5\u2010trifluorophenyl groups at the 3,3\u2032\u2010positions of the binaphthyl framework enabled this transformation with excellent yield and high enantioselectivity. The process tolerates aryl\u2010 and alkyl\u2010substituted amino alcohols and a variety of other substrates, affording the corresponding products in high enantioselectivity and with <jats:italic>s<\/jats:italic> factors up to &gt;500.<\/jats:p>","DOI":"10.1002\/anie.201909700","type":"journal-article","created":{"date-parts":[[2019,9,6]],"date-time":"2019-09-06T13:35:44Z","timestamp":1567776944000},"page":"16177-16180","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Chiral\u2010Organotin\u2010Catalyzed Kinetic Resolution of Vicinal Amino Alcohols"],"prefix":"10.1002","volume":"58","author":[{"given":"Hui","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0299-3953","authenticated-orcid":false,"given":"Wen\u2010Hua","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,9,30]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(00)00149-6"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol3030023"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc41666f"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9500038"},{"key":"e_1_2_2_6_1","unstructured":"For selected examples see:"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0482435"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja057498v"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja901058u"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201305926"},{"key":"e_1_2_2_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201305926"},{"key":"e_1_2_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4100595"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12213"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812968"},{"key":"e_1_2_2_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201812968"},{"key":"e_1_2_2_14_1","unstructured":"\u00a0"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00037a068"},{"key":"e_1_2_2_16_2","first-page":"131","volume-title":"Comprehensive Asymmetric Catalysis, Supplement 1","author":"Shibasaki M.","year":"2004"},{"key":"e_1_2_2_17_2","first-page":"2561","author":"Claudio C.","year":"2007","journal-title":"Eur. 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