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Herein, we reported a new compound, the first tin borate chloride, Sn<jats:sub>2<\/jats:sub>B<jats:sub>5<\/jats:sub>O<jats:sub>9<\/jats:sub>Cl (SBOC) with a large birefringence (0.168 at 546\u2005nm) measured by the polarizing microscope. Its birefringence is 16\u2005times that of the isostructural Ba<jats:sub>2<\/jats:sub>B<jats:sub>5<\/jats:sub>O<jats:sub>9<\/jats:sub>Cl (BBOC) compound (0.010@ at 546\u2005nm). The results show that the birefringence enhancement originates mainly from the Sn<jats:sup>2+<\/jats:sup> polyhedra. We propose that the birefringence can be enlarged by substituting the alkaline\u2010earth metal cation by the Sn<jats:sup>2+<\/jats:sup> cation in the isostructural borate with small birefringence. This strategy will guide the discovery of large birefringent materials in the future.<\/jats:p>","DOI":"10.1002\/anie.201911187","type":"journal-article","created":{"date-parts":[[2019,9,17]],"date-time":"2019-09-17T08:42:31Z","timestamp":1568709751000},"page":"17675-17678","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":256,"title":["Sn<sub>2<\/sub>B<sub>5<\/sub>O<sub>9<\/sub>Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline\u2010Earth\u2010Metal Substitution by Tin"],"prefix":"10.1002","volume":"58","author":[{"given":"Jingyu","family":"Guo","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Functional Materials and Devices for Special Environments Xinjiang Technical Institute of Physics &amp; Chemistry of CAS Xinjiang Key Laboratory of Electronic Information Materials and Devices  40-1 South Beijing Road Urumqi 830011 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abudukadi","family":"Tudi","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Functional Materials and Devices for Special Environments Xinjiang Technical Institute of Physics &amp; Chemistry of CAS Xinjiang Key Laboratory of Electronic Information Materials and Devices  40-1 South Beijing Road Urumqi 830011 China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shujuan","family":"Han","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Functional Materials and Devices for Special Environments Xinjiang Technical Institute of Physics &amp; Chemistry of CAS Xinjiang Key Laboratory of Electronic Information Materials and Devices  40-1 South Beijing Road Urumqi 830011 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihua","family":"Yang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Functional Materials and Devices for Special Environments Xinjiang Technical Institute of Physics &amp; Chemistry of CAS Xinjiang Key Laboratory of Electronic Information Materials and Devices  40-1 South Beijing Road Urumqi 830011 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4521-4507","authenticated-orcid":false,"given":"Shilie","family":"Pan","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Functional Materials and Devices for Special Environments Xinjiang Technical Institute of Physics &amp; Chemistry of CAS Xinjiang Key Laboratory of Electronic Information Materials and Devices  40-1 South Beijing Road Urumqi 830011 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,10,4]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1117\/3.626141"},{"key":"e_1_2_2_2_1","volume-title":"Polarized Light","author":"Goldstein D. 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