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Cages of the nanosheets are in situ incorporated with copper oxide clusters. The CuO@SAPO\u201034 nanosheets exhibit a large external surface area with a high number of (010) channel pores on the surface. Due to the thin morphology, copper oxide clusters occupy the outmost cages with a probability &gt;50\u2009%. The distinctive configuration facilitates a new concept of pore mouth catalysis, i.e., reactant molecules larger than the pores cannot enter the interior of the molecular sieves but can interact with the CuO clusters at \u201cthe mouth\u201d of the pore. In heterogeneous catalysis, CuO@SAPO\u201034 nanosheets have shown top performance in one\u2010pot oxidation of cyclohexane to adipic acid by O<jats:sub>2<\/jats:sub>, a key compound for the manufacture of nylon\u201066, which is so far produced using non\u2010green nitric acid oxidation.<\/jats:p>","DOI":"10.1002\/anie.201911749","type":"journal-article","created":{"date-parts":[[2019,12,9]],"date-time":"2019-12-09T09:16:12Z","timestamp":1575882972000},"page":"2606-2611","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Morphology\u2010Reserved Synthesis of Discrete Nanosheets of CuO@SAPO\u201034 and Pore Mouth Catalysis for One\u2010Pot Oxidation of Cyclohexane"],"prefix":"10.1002","volume":"59","author":[{"given":"Xiangke","family":"Guo","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Nanjing University  Nanjing 210023 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