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Ketones (43 substrates) are reduced to alcohols in high yields (up to &gt;99\u2009%) and with excellent enantioselectivities (90\u201399\u2009% <jats:italic>ee<\/jats:italic>). A stereochemical model based on attractive CH\u2013\u03c0 interactions is proposed.<\/jats:p>","DOI":"10.1002\/anie.201912605","type":"journal-article","created":{"date-parts":[[2019,11,14]],"date-time":"2019-11-14T17:31:16Z","timestamp":1573752676000},"page":"187-191","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Retracted: The Manganese(I)\u2010Catalyzed Asymmetric Transfer Hydrogenation of Ketones: Disclosing the Macrocylic Privilege"],"prefix":"10.1002","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1995-0666","authenticated-orcid":false,"given":"Alessandro","family":"Passera","sequence":"first","affiliation":[{"name":"Departement Chemie und Angewandte Biowissenschaften Eidgen\u00f6ssische Technische Hochschule (ETH) Z\u00fcrich  8093 Z\u00fcrich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1824-7760","authenticated-orcid":false,"given":"Antonio","family":"Mezzetti","sequence":"additional","affiliation":[{"name":"Departement Chemie und Angewandte Biowissenschaften Eidgen\u00f6ssische Technische Hochschule (ETH) Z\u00fcrich  8093 Z\u00fcrich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,11,29]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","volume-title":"Catalysis Without Precious Metals","year":"2010"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1247240"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar500345f"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00385"},{"key":"e_1_2_2_6_2","volume-title":"Non-Noble Metal Catalysis: Molecular Approaches and 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