{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:29:09Z","timestamp":1786976949322,"version":"build-2736575974"},"reference-count":72,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2019,11,27]],"date-time":"2019-11-27T00:00:00Z","timestamp":1574812800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012498","name":"Energy System Integration, Paul Scherrer Institut","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012498","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,1,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The reaction of methane with copper\u2010exchanged mordenite with two different Si\/Al ratios was studied by means of in\u2005situ NMR and infrared spectroscopies. The detection of NMR signals was shown to be possible with high sensitivity and resolution, despite the presence of a considerable number of paramagnetic Cu\n                    <jats:sup>II<\/jats:sup>\n                    species. Several types of surface\u2010bonded compounds were found after reaction, namely molecular methanol, methoxy species, dimethyl ether, mono\u2010 and bidentate formates, Cu\n                    <jats:sup>I<\/jats:sup>\n                    monocarbonyl as well as carbon monoxide and dioxide, which were present in the gas phase. The relative fractions of these species are strongly influenced by the reaction temperature and the structure of the copper sites and is governed by the Si\/Al ratio. While methoxy species bonded to Br\u00f8nsted acid sites, dimethyl ether and bidentate formate species are the main products over copper\u2010exchange mordenite with a Si\/Al ratio of 6; molecular methanol and monodentate formate species were observed mainly over the material with a Si\/Al ratio of 46. These observations are important for understanding the methane partial oxidation mechanism and for the rational design of the active materials for this reaction.\n                  <\/jats:p>","DOI":"10.1002\/anie.201912668","type":"journal-article","created":{"date-parts":[[2019,11,4]],"date-time":"2019-11-04T04:07:05Z","timestamp":1572840425000},"page":"910-918","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":70,"title":["Pathways of Methane Transformation over Copper\u2010Exchanged Mordenite as Revealed by In\u2005Situ NMR and IR Spectroscopy"],"prefix":"10.1002","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3788-8969","authenticated-orcid":false,"given":"Vitaly L.","family":"Sushkevich","sequence":"first","affiliation":[{"name":"Laboratory for Catalysis and Sustainable Chemistry Paul Scherrer Institut  5232 Villigen PSI Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ren\u00e9","family":"Verel","sequence":"additional","affiliation":[{"name":"Institute for Chemistry and Bioengineering ETH Zurich  Vladimir-Prelog-Weg 1 8093 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jeroen A.","family":"van Bokhoven","sequence":"additional","affiliation":[{"name":"Laboratory for Catalysis and Sustainable Chemistry Paul Scherrer Institut  5232 Villigen PSI Switzerland"},{"name":"Institute for Chemistry and Bioengineering ETH Zurich  Vladimir-Prelog-Weg 1 8093 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,11,27]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-2991(97)80320-5"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.280.5363.560"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00428"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.6b00534"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY01229B"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01683"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(03)00648-3"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60259A"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2016.12.006"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja903930e"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00226"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702550"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201702550"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4760"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja047158u"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2005.09.028"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0910461106"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja106283u"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2011.10.009"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C1CC15840F"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b02817"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8546"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC08371K"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aam9035"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802922"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201802922"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY01055B"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2019.01.040"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511065"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201511065"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201700768"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201801809"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC09645B"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC07893A"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b03005"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06472"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2018.07.028"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b08071"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b01895"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b01534"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.6b00139"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b05139"},{"key":"e_1_2_6_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY02461D"},{"key":"e_1_2_6_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b00986"},{"key":"e_1_2_6_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2009.11.012"},{"key":"e_1_2_6_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC03921F"},{"key":"e_1_2_6_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/cmr.10035"},{"key":"e_1_2_6_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-444-63506-8.00004-5"},{"key":"e_1_2_6_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp4006795"},{"key":"e_1_2_6_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800317"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800317"},{"key":"e_1_2_6_48_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1744723"},{"key":"e_1_2_6_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja061018y"},{"key":"e_1_2_6_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200700029"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200700029"},{"key":"e_1_2_6_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssnmr.2016.10.003"},{"key":"e_1_2_6_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp400331m"},{"key":"e_1_2_6_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-2991(08)64152-X"},{"key":"e_1_2_6_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar700210f"},{"key":"e_1_2_6_55_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2012.12.030"},{"key":"e_1_2_6_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp906888m"},{"key":"e_1_2_6_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2007.07.018"},{"key":"e_1_2_6_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1387-1811(98)00323-0"},{"key":"e_1_2_6_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201406823"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201406823"},{"key":"e_1_2_6_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp000584r"},{"key":"e_1_2_6_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp066732g"},{"key":"e_1_2_6_62_1","doi-asserted-by":"publisher","DOI":"10.1023\/B:CATL.0000023721.90964.e2"},{"key":"e_1_2_6_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(97)00221-4"},{"key":"e_1_2_6_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(96)00267-0"},{"key":"e_1_2_6_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201903802"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201903802"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201912668","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201912668","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.201912668","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201912668","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,6]],"date-time":"2023-09-06T21:23:32Z","timestamp":1694035412000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201912668"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,11,27]]},"references-count":72,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2020,1,7]]}},"alternative-id":["10.1002\/anie.201912668"],"URL":"https:\/\/doi.org\/10.1002\/anie.201912668","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,11,27]]},"assertion":[{"value":"2019-10-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-11-27","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}