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These pillar[5]arene\u2010derived structures display both unique conformational freedom, differing from that of pillararenes, with a rich blend of solid\u2010state conformations and excellent host\u2013guest interactions in solution. Finally we show how this novel macrocyclic scaffold can be functionalized in a variety of ways and used as functional crystalline materials to distinguish uniquely between benzene and cyclohexane.<\/jats:p>","DOI":"10.1002\/anie.201913055","type":"journal-article","created":{"date-parts":[[2019,11,25]],"date-time":"2019-11-25T12:05:57Z","timestamp":1574683557000},"page":"3994-3999","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":206,"title":["Tiara[5]arenes: Synthesis, Solid\u2010State Conformational Studies, Host\u2013Guest Properties, and Application as Nonporous Adaptive Crystals"],"prefix":"10.1002","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3062-6023","authenticated-orcid":false,"given":"Weiwei","family":"Yang","sequence":"first","affiliation":[{"name":"Institute for Molecular Design and Synthesis School of Pharmaceutical Science &amp; Technology Tianjin University  92 Weijin Road, Nankai District Tianjin 300072 P. 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see:"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo100273n"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1080\/10610278.2013.822973"},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.comptc.2019.05.011"},{"key":"e_1_2_6_61_1","unstructured":"Crystallographic data for T[5]-(OMe)5: C40H40O5; colorless block 0.2\u00d70.2\u00d70.2\u2005mm3; triclinic space groupP;a=11.30470(10) b=12.60500(10);c=12.78350(10)\u2005\u00c5;\u03b1=76.1580(10) \u03b2=88.8410(10) \u03b3=66.9490(10)\u00b0;V=1621.97(3)\u2005\u00c53;Z=2;\u03c1calc=1.230\u2005g\u2009cm\u22123; 2\u03b8max=149.378;T=160(10)\u2005K; 45\u2009791 reflections collected 6363 independent 411 parameters;\u03bc=0.634\u2005mm\u22121;R1=0.0513 [I>2\u03c3(I)] wR2=0.1472 (all data).[37]"},{"key":"e_1_2_6_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805980"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201805980"},{"key":"e_1_2_6_63_1","unstructured":"Crystallographic data for CH3CN\u2282T[5]-(OMe)5: C42H43NO5; 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