{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,14]],"date-time":"2026-01-14T00:38:20Z","timestamp":1768351100269,"version":"3.49.0"},"reference-count":33,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2019,12,30]],"date-time":"2019-12-30T00:00:00Z","timestamp":1577664000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2020,2,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Cyanogen diluted in argon was reacted with laser ablated Zn atoms to produce the NCZnCN and NCZnZnCN cyanides and higher energy isocyanides ZnNC, CNZnNC, and CNZnZnNC, which were isolated in excess argon at 4\u2005K. These reaction products, identified from the matrix infrared spectra of their \u2010CN and \u2010NC chromophore ligand stretching modes, were confirmed by <jats:sup>13<\/jats:sup>C and <jats:sup>15<\/jats:sup>N isotopic substitution and comparison with frequencies calculated by the B3LYP and CCSD(T) methods using the all electron aug\u2010cc\u2010pVTZ basis sets. The cyanide and isocyanide products were increased markedly by mercury arc UV photolysis, which covers the zinc atomic absorption. The above electronic structure calculations that produce appropriate ligand frequencies for these dizinc products also provide their Zn\u2212Zn bond lengths: CCSD(T) calculations find a short 2.367\u2005\u00c5 Zn\u2212Zn bond in the NCZnZnCN cyanide, a shorter 2.347\u2005\u00c5 Zn\u2212Zn bond in the 37.4\u2005kJ\u2009mol<jats:sup>\u22121<\/jats:sup> higher energy isocyanide CNZnZnNC, and a longer 4.024\u2005\u00c5 bond in the dizinc van der Waals dimer. Thus, the diatomic cyanide (\u2010CN) and isocyanide (\u2010NC) ligands are as capable of stabilizing the Zn\u2212Zn bond as many much larger ligands based on their measured and our calculated Zn\u2212Zn bond lengths. This is the first example of dizinc complexes stabilized by different ligand isomers. Additional weaker bands in this region can be assigned to the analogous trizinc molecules NCZnZnZnCN and CNZnZnZnNC.<\/jats:p>","DOI":"10.1002\/anie.201914153","type":"journal-article","created":{"date-parts":[[2019,12,5]],"date-time":"2019-12-05T06:30:02Z","timestamp":1575527402000},"page":"2496-2504","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Formation of Short Zn\u2212Zn Bonds Stabilized by Simple Cyanide and Isocyanide Ligands"],"prefix":"10.1002","volume":"59","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6306-0340","authenticated-orcid":false,"given":"Lester","family":"Andrews","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Virginia  Charlottesville VA 22904 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Han\u2010Gook","family":"Cho","sequence":"additional","affiliation":[{"name":"Department of Chemistry Incheon National University  119 Academy-ro Yeonsu-gu Incheon 22012 South Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,12,30]]},"reference":[{"key":"e_1_2_6_1_1","first-page":"3","volume-title":"Advanced Inorganic Chemistry","author":"Cotton F. A.","year":"1999"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1101356"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1102500"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0668217"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704568"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704568"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs15343b"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja072682x"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/b904478g"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00297"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100020a014"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp046414m"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201504818"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201504818"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC09946J"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b00196"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.8b02036"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.8b06810"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.7b09291"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.9b01286"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904727"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201904727"},{"key":"e_1_2_6_20_1","unstructured":"Gaussian\u200916 Revision\u2009A.03 M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone G.\u2005A. Petersson H. Nakatsuji et\u2005al. Gaussian Inc. Wallingford CT 2016."},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.453520"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1998907"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2852(77)90362-9"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3049444"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/om060318l"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/jrs.1640"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00160a038"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464244"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.23266"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fanie.201914153","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201914153","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.201914153","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.201914153","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,7]],"date-time":"2023-09-07T17:54:27Z","timestamp":1694109267000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201914153"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,12,30]]},"references-count":33,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2020,2,3]]}},"alternative-id":["10.1002\/anie.201914153"],"URL":"https:\/\/doi.org\/10.1002\/anie.201914153","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,12,30]]},"assertion":[{"value":"2019-11-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-12-30","order":2,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}